Multiple sulphur and lead sources recorded in hydrothermal exhalites associated with the Lemarchant volcanogenic massive sulphide deposit, central Newfoundland, Canada

• Published in: Mineralium Deposita
• Main Authors: Lode, Stefanie, Piercey, Stephen J., Layne, Graham D., Piercey, Glenn, Cloutier, Jonathan
• Format: Article in Journal/Newspaper
• Language: English
• Published: 2017
• Subjects: VMS; Exhalites; Sulphur and lead isotopes; TSR; BSR; BSO; Disproportionation; Canada; Newfoundland
• Online Access: https://research-portal.st-andrews.ac.uk/en/researchoutput/multiple-sulphur-and-lead-sources-recorded-in-hydrothermal-exhalites-associated-with-the-lemarchant-volcanogenic-massive-sulphide-deposit-central-newfoundland-canada(416a225a-b286-4355-8afc-8f1d6e5b5006).html; https://doi.org/10.1007/s00126-016-0652-1; https://research-repository.st-andrews.ac.uk/bitstream/10023/10616/1/Lode_et_al_2016_pre_layout.pdf

Metalliferous sedimentary rocks (mudstones, exhalites) associated with the Cambrian precious metal-bearing Lemarchant Zn-Pb-Cu-Au-Ag-Ba volcanogenic massive sulphide (VMS) deposit, Tally Pond volcanic belt, precipitated both before and after VMS mineralization. Sulphur and Pb isotopic studies of sulphides within the Lemarchant exhalites provide insight into the sources of S and Pb in the exhalites as a function of paragenesis and evolution of the deposit and subsequent post-depositional modification. In situ S isotope microanalyses of polymetallic sulphides (euhedral and framboidal pyrite, anhedral chalcopyrite, pyrrhotite, galena and euhedral arsenopyrite) by secondary ion mass spectrometry (SIMS) yielded δ 34 S values ranging from −38.8 to +14.4 ‰, with an average of ∼ −12.8 ‰. The δ 34 S systematics indicate sulphur was predominantly biogenically derived via microbial/biogenic sulphate reduction of seawater sulphate, microbial sulphide oxidation and microbial disproportionation of intermediate S compounds. These biogenic processes are coupled and occur within layers of microbial mats consisting of different bacterial/archaeal species, i.e., sulphate reducers, sulphide oxidizers and those that disproportionate sulphur compounds. Inorganic processes or sources (i.e., thermochemical sulphate reduction of seawater sulphate, leached or direct igneous sulphur) also contributed to the S budget in the hydrothermal exhalites and are more pronounced in exhalites that are immediately associated with massive sulphides. Galena Pb isotopic compositions by SIMS microanalysis suggest derivation of Pb from underlying crustal basement (felsic volcanic rocks of Sandy Brook Group), whereas less radiogenic Pb derived from juvenile sources leached from mafic volcanic rocks of the Sandy Brook Group and/or Tally Pond group. This requires that the hydrothermal fluids interacted with juvenile and evolved crust during hydrothermal circulation, which is consistent with the existing tectonic model that suggests a formation of the Tally ...