Statistical extraction of volcanic sulphate from non-Polar ice cores

Ice cores from outside the Greenland and Antarctic ice sheets are difficult to date because of seasonal melting and multiple sources (terrestrial, marine, biogenic and anthropogenic) of sulfates deposited onto the ice. Here we present a method of volcanic sulfate extraction that relies on fitting su...

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Bibliographic Details
Main Authors: Moore, J.C., Beaudon, E., Kang, S., Divine, D., Isaksson, E., Pohjola, V.A., van de Wal, R.S.W.
Other Authors: Marine and Atmospheric Research, Dep Natuurkunde
Format: Article in Journal/Newspaper
Language:English
Published: 2012
Subjects:
Online Access:https://dspace.library.uu.nl/handle/1874/242381
Description
Summary:Ice cores from outside the Greenland and Antarctic ice sheets are difficult to date because of seasonal melting and multiple sources (terrestrial, marine, biogenic and anthropogenic) of sulfates deposited onto the ice. Here we present a method of volcanic sulfate extraction that relies on fitting sulfate profiles to other ion species measured along the cores in moving windows in log space. We verify the method with a well dated section of the Belukha ice core from central Eurasia. There are excellent matches to volcanoes in the preindustrial, and clear extraction of volcanic peaks in the post-1940 period when a simple method based on calcium as a proxy for terrestrial sulfate fails due to anthropogenic sulfate deposition. We then attempt to use the same statistical scheme to locate volcanic sulfate horizons within three ice cores from Svalbard and a core from Mount Everest. Volcanic sulfate is