Genesis of monazite-rich, orthopyroxene-bearing veins in the Kliphoog area of the Concordia Granite, Springbok, Namaqualand, South Africa: Sources, fluids, and the mobility of actinides and REE

• Main Authors: Harlov, Daniel, Ballouard, Christophe, Elburg, Marlina, Knoper, Michael, Wilke, Franziska, Ning, Wen Bin, Andreoli, Marco A.G.
• Other Authors: German Research Centre for Geosciences - Helmholtz-Centre Potsdam (GFZ), GeoRessources, Institut national des sciences de l'Univers (INSU - CNRS)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), Géosciences Rennes (GR), Université de Rennes (UR)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Rennes (OSUR), Université de Rennes (UR)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Rennes 2 (UR2)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Rennes 2 (UR2)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Centre National de la Recherche Scientifique (CNRS), University of Johannesburg South Africa (UJ), State Key Laboratory of Geological Processes and Mineral Resources Wuhan (GPMR), China University of Geosciences Wuhan (CUG), University of the Witwatersrand Johannesburg (WITS), ANR-10-LABX-0021,RESSOURCES21,Strategic metal resources of the 21st century(2010)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2020
• Subjects: Zircon; Monazite; Fluids; REE; Granite; South Africa; [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry; [SDU.STU.MI]Sciences of the Universe [physics]/Earth Sciences/Mineralogy; North Cape
• Online Access: https://cnrs.hal.science/hal-04627216; https://doi.org/10.1016/j.lithos.2020.105762

International audience A network of monazite-rich, coarse-grained veins and fine-grained veins permeating the mid-Proterozoic Concordia Granite in the Kliphoog area near Springbok, Namaqualand, North Cape Province, South Africa, are describedwith respect to theirwhole-rock chemistry, petrography, mineralogy, andmineral chemistry along with zircon andmonazite geochronology. Chondrite-normalized trace element data indicate that the coarse-grained veins are enriched in LREE relative to the Concordia GranitewithHREE enrichment being somewhat variable.HREE in altered Concordia Granite, at the contact with the coarse-grained vein, are heavily depleted compared to unaltered Concordia Granite while the LREE show the same approximate abundances. Chloritization is common in the coarse-grained veins along mineral grain boundaries with chlorite replacing most of the orthopyroxene megacrysts, though occasional remnants of orthopyroxene remain in the core. A traverse across one of the coarse-grained veins showed no obvious mineral chemical trends between the vein and surrounding granite. Relic Fe-richmegacryst orthopyroxene has an Al2O3 content of around 2.0 wt% suggesting formation at around 700 °C. The Fe-rich biotite has mean Ti values ranging from TiO2=4.1 to 1.2 wt% indicating formation at 700–800 °C. The coarse-grained veins and fine-grained veins are characterized by abundant accessory Th-rich monazite, heterogeneously distributed in the veins. Lesser amounts of monazite are found in the granite. Other accessory minerals in the veins and granite include zircon and rare fluorapatite. Back-scattered electron imaging shows that the anhedral to euhedral monazite grains (up to more than 1500 μm in size) tend to be complexly zoned with light and dark areas. Lighter areas are more enriched in Th and/or Ce than darker areas. This complex zoning can occur as magmatic/sector zoning and more commonly as a complex series of metasomatic alteration events. Metasomatic textures, which are due to variable fluid-induced mobility of ...