Influence of iron aggregation on the catalytic performance of desilicated MFI in the DeNO(x) process

• Published in: Microporous and Mesoporous Materials
• Main Authors: Rutkowska, M., Borcuch, A., Marzec, A., Kowalczyk, A., Samojeden, B., Moreno, J.M., DÍAZ MORALES, URBANO MANUEL, Chmielarz, L.
• Other Authors: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química, National Science Centre, Polonia, Agencia Estatal de Investigación, Ministerstwo Edukacji i Nauki, Polonia
• Format: Article in Journal/Newspaper
• Language: English
• Published: Elsevier 2020
• Subjects: Iron aggregation; Oligocations; Mesoporous MFI; DeNO(x) process; Kowalczyk; Morales; Moreno; samojed*
• Online Access: http://hdl.handle.net/10251/176437; https://doi.org/10.1016/j.micromeso.2018.09.015

[EN] In the present study, an influence of the iron aggregation in conventional and micro-mesoporous MFI on their catalytic activity in the NO reduction with ammonia (DeNO(x) process) was studied. Modification of MFI zeolite properties was done by the desilication in the presence of NaOH and TPAOH (tertapropylammonium hydroxide). In the next step, the samples were modified with iron by ion-exchange with the use of a conventional solution of Fe cations (FeSO4) and a solution of iron triple-metallic aggregates (oligocations) ([Fe-3(OAc)(6)O(H2O)(3)](+)). Both of the applied modification techniques (desilication and modification with Fe-3 oligocations) increased the catalytic activity of the MFI zeolite in the DeNO(x) process. This increased catalytic activity was connected with changes in sample porosity, Si/Al ratio, topology, as well as aggregation and dispersion of iron species on the catalyst surface, which was investigated by N-2-sorption, XRD, ICP, NMR, HRTEM and UV-vis-DRS techniques. This work was carried out in the frame of project No. 0670/IP3/2016/74 from the Polish Ministry of Science and Higher Education in the years 2016-2019 and in the frame of project No. 2012/05/B/ST5/00269 from the National Science Centre (Poland). U. D. acknowledges to the Spanish Government by the funding (MAT2017-82288-C2-1-P). Rutkowska, M.; Borcuch, A.; Marzec, A.; Kowalczyk, A.; Samojeden, B.; Moreno, J.; Díaz Morales, UM. (2020). Influence of iron aggregation on the catalytic performance of desilicated MFI in the DeNO(x) process. Microporous and Mesoporous Materials. 304:1-8. https://doi.org/10.1016/j.micromeso.2018.09.015 1 8 304