Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system
Immobilized Candida antarctica lipase-catalyzed esterification of adipic acid and oleyl alcohol was investigated in a solvent-free system (SFS). Optimum conditions for adipate ester synthesis in a stirred-tank reactor were determined by the response surface methodology (RSM) approach with respect to...
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ftunivpmalaysia:oai:psasir.upm.edu.my:15995 2023-05-15T13:42:02+02:00 Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system Chaibakhsh, Naz Abdul Rahman, Mohd Basyaruddin Abd. Aziz, Suraini Basri, Mahiran Salleh, Abu Bakar Raja Abdul Rahman, Raja Noor Zaliha 2009 application/pdf http://psasir.upm.edu.my/15995/ http://psasir.upm.edu.my/15995/1/Optimized%20lipase%20catalyzed%20synthesis%20of%20adipate%20ester%20in%20a%20solvent.pdf unknown Springer http://psasir.upm.edu.my/15995/1/Optimized%20lipase%20catalyzed%20synthesis%20of%20adipate%20ester%20in%20a%20solvent.pdf Chaibakhsh, Naz and Abdul Rahman, Mohd Basyaruddin and Abd. Aziz, Suraini and Basri, Mahiran and Salleh, Abu Bakar and Raja Abdul Rahman, Raja Noor Zaliha (2009) Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system. Journal of Industrial Microbiology & Biotechnology, 36 (9). pp. 1149-1155. ISSN 1367-5435; ESSN: 1476-5535 Article PeerReviewed 2009 ftunivpmalaysia 2017-06-20T14:58:41Z Immobilized Candida antarctica lipase-catalyzed esterification of adipic acid and oleyl alcohol was investigated in a solvent-free system (SFS). Optimum conditions for adipate ester synthesis in a stirred-tank reactor were determined by the response surface methodology (RSM) approach with respect to important reaction parameters including time, temperature, agitation speed, and amount of enzyme. A high conversion yield was achieved using low enzyme amounts of 2.5% w/w at 60C, reaction time of 438 min, and agitation speed of 500 rpm. The good correlation between predicted value (96.0%) and actual value (95.5%) implies that the model derived from RSM allows better understanding of the effect of important reaction parameters on the lipase-catalyzed synthesis of adipate ester in an organic solvent-free system. Higher volumetric productivity compared to a solvent-based system was also offered by SFS. The results demonstrate that the solvent-free system is efficient for enzymatic synthesis of adipate ester. Article in Journal/Newspaper Antarc* Antarctica Universiti Putra Malaysia: PSAS (Perpuskataan Sultan Abuld Samad) Institutional Repository |
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Universiti Putra Malaysia: PSAS (Perpuskataan Sultan Abuld Samad) Institutional Repository |
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ftunivpmalaysia |
language |
unknown |
description |
Immobilized Candida antarctica lipase-catalyzed esterification of adipic acid and oleyl alcohol was investigated in a solvent-free system (SFS). Optimum conditions for adipate ester synthesis in a stirred-tank reactor were determined by the response surface methodology (RSM) approach with respect to important reaction parameters including time, temperature, agitation speed, and amount of enzyme. A high conversion yield was achieved using low enzyme amounts of 2.5% w/w at 60C, reaction time of 438 min, and agitation speed of 500 rpm. The good correlation between predicted value (96.0%) and actual value (95.5%) implies that the model derived from RSM allows better understanding of the effect of important reaction parameters on the lipase-catalyzed synthesis of adipate ester in an organic solvent-free system. Higher volumetric productivity compared to a solvent-based system was also offered by SFS. The results demonstrate that the solvent-free system is efficient for enzymatic synthesis of adipate ester. |
format |
Article in Journal/Newspaper |
author |
Chaibakhsh, Naz Abdul Rahman, Mohd Basyaruddin Abd. Aziz, Suraini Basri, Mahiran Salleh, Abu Bakar Raja Abdul Rahman, Raja Noor Zaliha |
spellingShingle |
Chaibakhsh, Naz Abdul Rahman, Mohd Basyaruddin Abd. Aziz, Suraini Basri, Mahiran Salleh, Abu Bakar Raja Abdul Rahman, Raja Noor Zaliha Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system |
author_facet |
Chaibakhsh, Naz Abdul Rahman, Mohd Basyaruddin Abd. Aziz, Suraini Basri, Mahiran Salleh, Abu Bakar Raja Abdul Rahman, Raja Noor Zaliha |
author_sort |
Chaibakhsh, Naz |
title |
Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system |
title_short |
Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system |
title_full |
Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system |
title_fullStr |
Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system |
title_full_unstemmed |
Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system |
title_sort |
optimized lipase catalyzed synthesis of adipate ester in a solvent-free system |
publisher |
Springer |
publishDate |
2009 |
url |
http://psasir.upm.edu.my/15995/ http://psasir.upm.edu.my/15995/1/Optimized%20lipase%20catalyzed%20synthesis%20of%20adipate%20ester%20in%20a%20solvent.pdf |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
http://psasir.upm.edu.my/15995/1/Optimized%20lipase%20catalyzed%20synthesis%20of%20adipate%20ester%20in%20a%20solvent.pdf Chaibakhsh, Naz and Abdul Rahman, Mohd Basyaruddin and Abd. Aziz, Suraini and Basri, Mahiran and Salleh, Abu Bakar and Raja Abdul Rahman, Raja Noor Zaliha (2009) Optimized lipase catalyzed synthesis of adipate ester in a solvent-free system. Journal of Industrial Microbiology & Biotechnology, 36 (9). pp. 1149-1155. ISSN 1367-5435; ESSN: 1476-5535 |
_version_ |
1766161969452154880 |