Carbon dioxide emissions by rock organic carbon oxidation and the net geochemical carbon budget of the Mackenzie River Basin

• Published in: American Journal of Science
• Main Authors: Horan, Kate, Hilton, Robert, Dellinger, Mathieu, Tipper, Ed, Galy, Valier, Calmels, Damien, Selby, David, Gaillardet, Jérôme, Ottley, Chris, Parsons, Daniel, Burton, Kevin
• Other Authors: Durham University, Energy and Environment Institute, University of Hull, Department of Earth Sciences USC Los Angeles, University of Southern California (USC), Woods Hole Oceanographic Institution (WHOI), Géosciences Paris Sud (GEOPS), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), Institut de Physique du Globe de Paris (IPGP), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS), Department of Earth Sciences Durham, University of Hull United Kingdom
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2019
• Subjects: [SDU]Sciences of the Universe [physics]; [SDU.STU]Sciences of the Universe [physics]/Earth Sciences; Arctic; Canada; Liard; Mackenzie River; Tsiigehtchic; Mackenzie river
• Online Access: https://hal.science/hal-02304778; https://doi.org/10.2475/06.2019.02

International audience The exposure of organic carbon in rocks to oxidative weathering can release carbon dioxide (CO2) to the atmosphere and consume atmospheric oxygen. Alongside volcanism, metamorphism, and the weathering of carbonate minerals by sulfuric acid, this is a major source of atmospheric CO2 over million year timescales. The balance between CO2 release and CO2 drawdown by silicate weathering and organic carbon burial sets the net geochemical carbon budget during weathering and erosion. However, the rates of rock-derived organic carbon (petrogenic organic carbon, OCpetro) oxidation remain poorly constrained. Here, we use rhenium as a proxy to trace and quantify CO2 release by OCpetro oxidation in the Mackenzie River Basin, Canada, where the other carbon fluxes have been well constrained previously. River water and sediment samples were collected between 2009 and 2013 at gauging stations along the Mackenzie River and its main tributaries (Liard, Peel and Arctic Red). To assess rhenium inputs from silicate, sulfide and OCpetro mineral phases we normalize dissolved rhenium concentrations, [Re]diss, to sodium and sulfate ion concentrations. This approach suggests that >85 percent of [Re]diss is derived from OCpetro in the main river channels. [Re]diss and water discharge measurements are used to quantify dissolved Re yields. River sediments provide a measure of the Re to OCpetro ratio of materials undergoing weathering in the basin, and agree well with published rock samples. Dissolved Re yields are combined with river sediment [Re]/[OCpetro] ratios to estimate the CO2 emissions by OCpetro weathering. These are 0.45 +0.19/−0.11 metric tonnes of carbon, tC km−2 yr−1for the Mackenzie River at Tsiigehtchic (3.8 +1.5/−0.9 × 104 moles km−2 yr−1), and 0.94 +0.41/−0.26 tC km−2 yr−1, 0.78 +0.35/−0.21 tC km−2 yr−1 and 1.01 +0.42/−0.25 tC km−2 yr−1 for the Peel, Arctic Red and Liard catchments, respectively. When considered alongside published silicate and carbonate weathering rates and the sedimentary burial ...