Evidence of calcium carbonates in coastal (Talos Dome and Ross Sea area) East Antarctica snow and firn: environmental and climatic implications.

• Published in: Earth and Planetary Science Letters
• Main Authors: SALA M, DELMONTE B, FREZZOTTI M, PROPOSITO M, SCARCHILLI C, MAGGI V, DAPIAGGI M, MARINO F, RICCI P. C, DE GIUDICI G., ARTIOLI, GILBERTO
• Other Authors: Sala, M, Delmonte, B, Frezzotti, M, Proposito, M, Scarchilli, C, Maggi, V, Artioli, Gilberto, Dapiaggi, M, Marino, F, RICCI P., C, DE GIUDICI, G.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Elsevier BV:PO Box 211, 1000 AE Amsterdam Netherlands:011 31 20 4853757, 011 31 20 4853642, 011 31 20 4853641, EMAIL: [e-mail], INTERNET: http://www.elsevier.nl, Fax: [phone] 2008
• Subjects: Antarc*; Antarctic; Antarctica; East Antarctica; Ross Sea; Sea ice
• Online Access: http://hdl.handle.net/11577/133711; https://doi.org/10.1016/j.epsl.2008.03.045

Micrometre-sized aeolian dust particles stored in Antarctic firn and ice layers are a useful tool for reconstructing climate and environmental changes in the past. The mineral content, particle concentration and chemical composition of modern dust in firn cores from the peripherycal dome (Talos Dome) and coastal area of East Antarctica (Ross Sea sector) were investigated. During analyses there was a considerable decrease in microparticle concentrations within a few hours of ice sample melting, accompanied by a systematic increase in the concentration of calcium ions (Ca2+) in solution. Based on mineralogical phase analyses, which reveal the presence of anhydrous and hydrous calcium carbonates such as calcite (CaCO3), monohydrocalcite (CaCO3·H2O) and ikaite (CaCO3·6H2O, hexahydrate calcium carbonate), the observed variations in concentrations are ascribed to the partial dissolution of the carbonate content of samples. Soluble carbonate compounds are thus primary aerosols included into the samples along with insoluble aluminosilicate minerals. We hypothesize hydrous carbonates may derive from the sea ice surface, where ikaite typically forms at the early stages of sea ice formation. Back trajectory calculations show that favourable events for air mass advection from the sea ice surface to Talos Dome are rare but likely to occur.