First investigations of IO, BrO, and NO2 summer atmospheric levels at a coastal East Antarctic site using mode-locked cavity enhanced absorption spectroscopy

• Published in: Geophysical Research Letters
• Main Authors: Grilli, Roberto, Legrand, Michel, Kukui, Alexandre, Méjean, Guillaume, Preunkert, Suzanne, Romanini, Daniele
• Other Authors: LAsers, Molécules et Environnement (LAME-LIPhy), Laboratoire Interdisciplinaire de Physique Saint Martin d’Hères (LIPhy), Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS), Université Joseph Fourier - Grenoble 1 (UJF), Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E), Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales Paris (CNES), Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS), National financial support and field logistic supplies for the summer campaign were provided by Institut Polaire Français-Paul Emile Victor (IPEV) within program 414, ANR-09-BLAN-0016,MoCaMAR(2009), ANR-09-BLAN-0226,OPALE(2009)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2013
• Subjects: Atmospheric oxidants; Antarctica; Radicals; [PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]; Antarc*; Antarctic; East Antarctica; West Antarctica
• Online Access: https://hal.science/hal-00996471; https://hal.science/hal-00996471/document; https://hal.science/hal-00996471/file/Grilli_et_al-2013-Geophysical_Research_Letters.pdf; https://doi.org/10.1002/GRL.50154

International audience IO, BrO, and NO2 were measured for the first time at Dumont d'Urville (East Antarctic coast) during summer 2011/2012 by using a near-UV-Visible laser spectrometer based on mode-locked cavity-enhanced absorption spectroscopy. IO mixing ratios ranged from the 2σ detection limit (0.04 pptv) up to 0.15 pptv. BrO remained close or below the detection limit (2 pptv) of the instrument. Daily averaged NO2 values ranged between the detection limit (10 pptv) and 60 pptv being far higher than levels of a few pptv commonly observed in the remote marine boundary layer. Data are discussed and compared with those available for another coastal Antarctic station (Halley, West Antarctica). It is shown that the oxidative capacity of the atmospheric boundary layer at coastal Antarctic sites is quite different in nature from West to East Antarctica, with the halogen chemistry being promoted at West and the OH chemistry at East.