Studies of volatile evolution in magmatic systems using melt inclusions

Understanding volatile evolution associated with active volcanic magmatic systems is of paramount importance because volatiles control and determine the magnitude of an eruption owing to the large change in molar volume that volatile species show depending on their physical state (volatiles dissolve...

Full description

Bibliographic Details
Main Author: ESPOSITO, ROSARIO
Other Authors: Esposito, R
Format: Doctoral or Postdoctoral Thesis
Language:English
Published: Università degli Studi di Milano-Bicocca 2012
Subjects:
Online Access:http://hdl.handle.net/10281/349369
Description
Summary:Understanding volatile evolution associated with active volcanic magmatic systems is of paramount importance because volatiles control and determine the magnitude of an eruption owing to the large change in molar volume that volatile species show depending on their physical state (volatiles dissolved in silicate melts vs. volatiles exsolved as vapor). For active volcanic systems studying the volatile evolution can help to assess the potential hazard associated to a certain locality. Also, volatile evolution in magmatic system controls the formation of certain ore deposits. Despite the importance of understanding volatile evolution of magmatic systems, concentrations of volatiles of evolving magmas are not easily available especially for magmas originated in the deep crust. Fortunately, sample of melts can be entrapped as melt inclusion (MI) into growing igneous minerals in crystalizing magma chamber. After the entrapment, the crystal works as an insulating capsule from the external magmatic environment. Researchers have started to use MI because they provide some advantages in respect to the classical whole rock approach to petrological studies. One of the most important advantages is that MI often represent sample of a deep and non-degassed melt (glass) available at Earth’s surface. This dissertation is a compilation of four publications produced during six years of research and is addressed to give a contribution in understanding the volatile evolution in magmatic systems and also to improve the present understanding of information that can be obtained using the melt inclusions technique. In the first chapter, I present an alternative interpretation of H2O-CO2 trends obtained from MI. In this study, we demonstrate that these trends can be due to post entrapment crystallization on the wall of the MI and not to magma ascent. This alternative view is more realistic especially for cases where in the same phenocrysts MI show strongly different CO2 concentrations. In the second chapter, I present a study to test for ...