Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol
Enantiomerically pure (R)- and (S)-1-benzoyloxypropane-2,3-diol have been prepared from (S)-(+)-2,2-dimethyl-1,3-dioxolane-4-methanol and used as reference compounds to correct the reported stereochemical outcome of the Candida antarctica lipase (CAL)-catalyzed benzoylation of glycerol.
| Published in: | Tetrahedron: Asymmetry |
|---|---|
| Main Authors: | , , |
| Other Authors: | |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Pergamon
2011
|
| Subjects: | |
| Online Access: | http://hdl.handle.net/2434/165093 https://doi.org/10.1016/j.tetasy.2011.04.003 |
| _version_ | 1821554866294620160 |
|---|---|
| author | CASATI, SILVANA P. Ciuffreda E. Santaniello |
| author2 | S. Casati P. Ciuffreda E. Santaniello |
| author_facet | CASATI, SILVANA P. Ciuffreda E. Santaniello |
| author_sort | CASATI, SILVANA |
| collection | The University of Milan: Archivio Istituzionale della Ricerca (AIR) |
| container_issue | 6 |
| container_start_page | 658 |
| container_title | Tetrahedron: Asymmetry |
| container_volume | 22 |
| description | Enantiomerically pure (R)- and (S)-1-benzoyloxypropane-2,3-diol have been prepared from (S)-(+)-2,2-dimethyl-1,3-dioxolane-4-methanol and used as reference compounds to correct the reported stereochemical outcome of the Candida antarctica lipase (CAL)-catalyzed benzoylation of glycerol. |
| format | Article in Journal/Newspaper |
| genre | Antarc* Antarctica |
| genre_facet | Antarc* Antarctica |
| id | ftunivmilanoair:oai:air.unimi.it:2434/165093 |
| institution | Open Polar |
| language | English |
| op_collection_id | ftunivmilanoair |
| op_container_end_page | 661 |
| op_doi | https://doi.org/10.1016/j.tetasy.2011.04.003 |
| op_relation | info:eu-repo/semantics/altIdentifier/wos/WOS:000291516900007 volume:22 issue:6 firstpage:658 lastpage:661 numberofpages:4 journal:TETRAHEDRON-ASYMMETRY http://hdl.handle.net/2434/165093 doi:10.1016/j.tetasy.2011.04.003 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-79956341065 |
| publishDate | 2011 |
| publisher | Pergamon |
| record_format | openpolar |
| spelling | ftunivmilanoair:oai:air.unimi.it:2434/165093 2025-01-16T19:04:55+00:00 Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol CASATI, SILVANA P. Ciuffreda E. Santaniello S. Casati P. Ciuffreda E. Santaniello 2011-03-30 http://hdl.handle.net/2434/165093 https://doi.org/10.1016/j.tetasy.2011.04.003 eng eng Pergamon info:eu-repo/semantics/altIdentifier/wos/WOS:000291516900007 volume:22 issue:6 firstpage:658 lastpage:661 numberofpages:4 journal:TETRAHEDRON-ASYMMETRY http://hdl.handle.net/2434/165093 doi:10.1016/j.tetasy.2011.04.003 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-79956341065 monobenzoyl glycerol asymmetric transesterification reduction Settore BIO/10 - Biochimica info:eu-repo/semantics/article 2011 ftunivmilanoair https://doi.org/10.1016/j.tetasy.2011.04.003 2024-01-23T23:22:03Z Enantiomerically pure (R)- and (S)-1-benzoyloxypropane-2,3-diol have been prepared from (S)-(+)-2,2-dimethyl-1,3-dioxolane-4-methanol and used as reference compounds to correct the reported stereochemical outcome of the Candida antarctica lipase (CAL)-catalyzed benzoylation of glycerol. Article in Journal/Newspaper Antarc* Antarctica The University of Milan: Archivio Istituzionale della Ricerca (AIR) Tetrahedron: Asymmetry 22 6 658 661 |
| spellingShingle | monobenzoyl glycerol asymmetric transesterification reduction Settore BIO/10 - Biochimica CASATI, SILVANA P. Ciuffreda E. Santaniello Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol |
| title | Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol |
| title_full | Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol |
| title_fullStr | Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol |
| title_full_unstemmed | Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol |
| title_short | Synthesis of enantiomerically pure (R)-and (S)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the Candida antarctica lipase-catalyzed benzoylation of glycerol |
| title_sort | synthesis of enantiomerically pure (r)-and (s)-1-benzoyloxypropane-2,3-diol and revision of the stereochemical outcome of the candida antarctica lipase-catalyzed benzoylation of glycerol |
| topic | monobenzoyl glycerol asymmetric transesterification reduction Settore BIO/10 - Biochimica |
| topic_facet | monobenzoyl glycerol asymmetric transesterification reduction Settore BIO/10 - Biochimica |
| url | http://hdl.handle.net/2434/165093 https://doi.org/10.1016/j.tetasy.2011.04.003 |