Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization
Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the...
Published in: | Macromolecular Symposia |
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Main Authors: | , , , |
Other Authors: | , |
Format: | Conference Object |
Language: | English |
Published: |
Wiley-VCH
2010
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Subjects: | |
Online Access: | https://biblio.ugent.be/publication/1202298 http://hdl.handle.net/1854/LU-1202298 https://doi.org/10.1002/masy.201051008 https://biblio.ugent.be/publication/1202298/file/1202327 |
Summary: | Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the enzyme, the monomer mixture containing methyl acrylate and the new monomers was polymerized via free radical polymerization resulting in a functional copolymer with M-n = 14500 g/mol. |
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