Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization

Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the...

Full description

Bibliographic Details
Published in:Macromolecular Symposia
Main Authors: Popescu, Dragos, Hoogenboom, Richard, Keul, Helmut, Möller, Martin
Other Authors: Stelzer, F, Wiesbrock, E
Format: Conference Object
Language:English
Published: Wiley-VCH 2010
Subjects:
Chemistry
DRUG-DELIVERY
TEMPERATURE
radical polymerization
functional monomers and polymers
enzyme-catalyzed transacylation
candida antarctica lipase-B
Antarc*
Antarctica
Online Access:https://biblio.ugent.be/publication/1202298
http://hdl.handle.net/1854/LU-1202298
https://doi.org/10.1002/masy.201051008
https://biblio.ugent.be/publication/1202298/file/1202327
Description
Summary:Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the enzyme, the monomer mixture containing methyl acrylate and the new monomers was polymerized via free radical polymerization resulting in a functional copolymer with M-n = 14500 g/mol.

Similar Items