Discovery of a natural CO 2 seep in the German North Sea: Implications for shallow dissolved gas and seep detection

A natural carbon dioxide (CO 2) seep was discovered during an expedition to the southern German North Sea (October 2008). Elevated CO 2 levels of ∼10–20 times above background were detected in seawater above a natural salt dome ∼30 km north of the East‐Frisian Island Juist. A single elevated value 5...

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Bibliographic Details
Published in:Journal of Geophysical Research
Main Authors: McGinnis, Daniel Frank, Schmidt, Mark, DelSontro, Tonya, Themann, Sören, Rovelli, Lorenzo, Reitz, Anja, Linke, Peter
Format: Article in Journal/Newspaper
Language:English
Published: 2011
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Online Access:https://archive-ouverte.unige.ch/unige:40710
Description
Summary:A natural carbon dioxide (CO 2) seep was discovered during an expedition to the southern German North Sea (October 2008). Elevated CO 2 levels of ∼10–20 times above background were detected in seawater above a natural salt dome ∼30 km north of the East‐Frisian Island Juist. A single elevated value 53 times higher than background was measured, indicating a possible CO 2 point source from the seafloor. Measured pH values of around 6.8 support modeled pH values for the observed high CO 2 concentration. These results are presented in the context of CO 2 seepage detection, in light of proposed subsurface CO 2 sequestering and growing concern of ocean acidification. We explore the boundary conditions of CO 2 bubble and plume seepage and potential flux paths to the atmosphere. Shallow bubble release experiments conducted in a lake combined with discrete‐bubble modeling suggest that shallow CO 2 outgassing will be difficult to detect as bubbles dissolve very rapidly (within meters). Bubble‐plume modeling further shows that a CO 2 plume will lose buoyancy quickly because of rapid bubble dissolution while the newly CO 2 ‐enriched water tends to sink toward the seabed. Results suggest that released CO 2 will tend to stay near the bottom in shallow systems (<200 m) and will vent to the atmosphere only during deep water convection (water column turnover). While isotope signatures point to a biogenic source, the exact origin is inconclusive because of dilution. This site could serve as a natural laboratory to further study the effects of carbon sequestration below the seafloor.