Geoquímica orgânica e palinofácies da formação barreirinha, Bacia do Amazonas, Brasil: paleoambiente e maturação térmica

The Amazon Basin is an intracratonic basin of Paleozoic age located in northern Brazil. It is known for being a pioneer area in oil exploration, being considered an area of new exploratory frontier. The shales of Fm. Barreirinha (Devonian) are hydrocarbon source rocks, with Mb. Abacaxis (Frasnian) b...

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Bibliographic Details
Main Author: Souza, Iasmine Maciel Silva
Other Authors: Teixeira, Leonardo Sena Gomes, orcid:0000-0003-0320-8299, http://lattes.cnpq.br/5061261000226463, Queiroz, Antônio Fernando de Souza, orcid:0000-0002-3473-4462, http://lattes.cnpq.br/8307874123800948, Garcia, Karina Santos, orcid:0000-0003-3575-311X, http://lattes.cnpq.br/5195190698719857, Dino, Rodolfo, http://lattes.cnpq.br/2263822390559538, Silva, Maristela Bagatin, http://lattes.cnpq.br/3423357030710071
Format: Thesis
Language:Portuguese
Published: Universidade Federal da Bahia 2022
Subjects:
Fid
Online Access:https://repositorio.ufba.br/handle/ri/37303
Description
Summary:The Amazon Basin is an intracratonic basin of Paleozoic age located in northern Brazil. It is known for being a pioneer area in oil exploration, being considered an area of new exploratory frontier. The shales of Fm. Barreirinha (Devonian) are hydrocarbon source rocks, with Mb. Abacaxis (Frasnian) being the most important generators. At the end of the deposition of the Paleozoic sequence, and with the beginning of the opening of the North Atlantic Ocean, the Penetecaua magmatism allowed extensive sills and diabase dykes to intrude into the sedimentary rocks of the Basin, mainly in the shales. The objective of this research was to evaluate the depositional paleoenvironment and the influence of heat from igneous activities on the maturation of organic matter, and on the potential for generating hydrocarbons in samples from two distinct outcrops of the Fm. Barreirinha: I) near the Monte Alegre Dome on the Northern border of the Basin, under the influence of igneous rocks; II) on the Southern border, with less effect of igneous rocks. Thirty-five samples were collected systematically, 12 located on the Northern border and 23 on the Southern border, of the Amazon Basin. The samples were submitted to determination of total organic carbon (TOC), Rock-Eval pyrolysis and analysis by gas chromatography with ionization detector (GC-FID), gas chromatography-mass spectrometry (GC-MS) (biomarkers), petrography and determination of stable isotopes of carbon (δ 13C). The results of the analyzes showed that the samples collected at the Northern border have excellent values of TOC, S2 ranging from moderate to excellent and are at the end of the oil generation window and beginning of gas generation. The kerogen was classified as type III, however, as the area generated light hydrocarbons, the TOC, S2 and IH values are residual. The results of saturated biomarker determinations indicate the marine origin of the organic matter, which was deposited in an anoxic to suboxic marine depositional paleoenvironment. The samples collected in ...