Glacial influence on the geochemistry of riverine iron fluxes to the Gulf of Alaska and effects of deglaciation

• Published in: Geophysical Research Letters
• Main Authors: Schroth, Andrew, W., Crusius, J., Chever, Fanny, Bostick, Benjamin, C., Rouxel, Olivier, J.
• Other Authors: United States Geological Survey Reston (USGS), Coastal and Marine Geology Program, University of Washington Seattle, Laboratoire des Sciences de l'Environnement Marin (LEMAR) (LEMAR), Institut de Recherche pour le Développement (IRD)-Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER)-Université de Brest (UBO)-Institut Universitaire Européen de la Mer (IUEM), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Université européenne de Bretagne - European University of Brittany (UEB), Lamont-Doherty Earth Observatory (LDEO), Columbia University New York, Domaines Océaniques (LDO), Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Observatoire des Sciences de l'Univers-Institut d'écologie et environnement-Centre National de la Recherche Scientifique (CNRS), Unité Géosciences Marines (GM), Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER), Department of Marine Chemistry and Geochemistry (WHOI), Woods Hole Oceanographic Institution (WHOI)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2011
• Subjects: boreal forest; glacier; iron; isotope; nutrient; speciation; [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry; [SDE.MCG]Environmental Sciences/Global Changes; Alaska
• Online Access: https://insu.hal.science/insu-00645879; https://insu.hal.science/insu-00645879/document; https://insu.hal.science/insu-00645879/file/GRL-Rouxel_al-2011.pdf; https://doi.org/10.1029/2011GL048367

International audience Riverine iron (Fe) derived from glacial weathering is a critical micronutrient source to ecosystems of the Gulf of Alaska (GoA). Here we demonstrate that the source and chemical nature of riverine Fe input to the GoA could change dramatically due to the widespread watershed deglaciation that is underway. We examine Fe size partitioning, speciation, and isotopic composition in tributaries of the Copper River which exemplify a long-term GoA watershed evolution from one strongly influenced by glacial weathering to a boreal-forested watershed. Iron fluxes from glacierized tributaries bear high suspended sediment and colloidal Fe loads of mixed valence silicate species, with low concentrations of dissolved Fe and dissolved organic carbon (DOC). Iron isotopic composition is indicative of mechanical weathering as the Fe source. Conversely, Fe fluxes from boreal-forested systems have higher dissolved Fe concentrations corresponding to higher DOC concentrations. Iron colloids and suspended sediment consist of Fe (hydr)oxides and organic complexes. These watersheds have an iron isotopic composition indicative of an internal chemical processing source. We predict that as the GoA watershed evolves due to deglaciation, so will the source, flux, and chemical nature of riverine Fe loads, which could have significant ramifications for Alaskan marine and freshwater ecosystems.