| Summary: | A primary goal of paleoclimatology is to extend the instrumental record to capture a wider range of natural variability, documenting the climate system's response to past changes that have no analog in the historical record. Sediment archives of the recent geologic past, both marine and lacustrine, offer the opportunity to study how climate responds to a range of forcings and changing boundary conditions on timescales ranging from years to millennia. In this dissertation I use lacustrine and marine sediment to investigate changes late Quaternary climate, with particular focus on the Last Interglacial period (LIG). First, I use multiple approaches to reconstruct long-term changes in the West African Monsoon by investigating centennial-scale hydrologic variability recorded in Lake Bosumtwi sediments over the past 530,000 years. Over this interval, hydrology in the region is driven by a complex interplay of orbital forcing and glacial-interglacial boundary conditions. Lake level was generally much lower between 50 and 300 ka, likely due to the redistribution of rainfall from the tropics to the subtropics, driven by eccentricity's amplification of precession. Consequently, the Holocene highstand at the lake was both larger and longer lived than the maximum highstand during the LIG.Annual layers were continuously deposited through the LIG in Lake Bosumtwi, and I also present a new, 12,100 year-long, varve record spanning the interval from 128.6 to 116.5 ka. Over the course of the LIG, lake level generally tracks sea surface temperatures (SST) in Gulf of Guinea, including an abrupt drop in lake level that lasted about 500 years ca. 118 ka, coincident with cool SSTs in the North Atlantic and severe aridity in Europe. I find that the despite the generally drier conditions, hydrology varied on similar timescales as the late Holocene, with pronounced multidecadal to centennial-scale variability with non-stationary periodicities. I also investigate the contribution of ocean thermal expansion to sea level rise during the LIG, using a synthesis of paleoceanographic data and a climate model simulation. Globally, LIG SSTs were similar to, or slightly cooler than late Holocene SSTs, with the exception of the North Atlantic, which was several degrees warmer. Consequently, thermal expansion was likely a minor component of sea level rise during the interval, explaining between -0.3 and 0.4 m. of the 6 to 8 m highstand. Lastly, I tested the potential of Raman spectroscopy as a new, non-destructive technique to rapidly measure oxygen isotopic ratios in carbonates at extremely high resolution. Analyses on a suite a synthetic calcites indicate that ¹⁸O/¹⁶O ratios can be measured directly from the Raman spectra and have a 1:1 correspondence with traditional mass-spectrometry measurements. At present, the technique does not have the precision necessary to record natural variability, although there is considerable potential for improving the precision of the technique. Release after 09-Jul-2014
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