A biocatalytic approach towards sustainable furanic-aliphatic polyesters

An eco-friendly approach towards furanic-aliphatic polyesters as sustainable alternatives to aromatic-aliphatic polyesters is presented. In this approach, biobased dimethyl 2,5-furandicarboxylate (DMFDCA) is polymerized with various (potentially) renewable aliphatic diols via Candida antarctica Lipa...

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Bibliographic Details
Published in:Polymer Chemistry
Main Authors: Jiang, Yi, Woortman, Albert J. J., van Ekenstein, Gert O. R. Alberda, Loos, Katja
Format: Article in Journal/Newspaper
Language:English
Published: 2015
Subjects:
ANTARCTICA LIPASE B
GLYCOL DIMETHACRYLATE) RESINS
RENEWABLE RESOURCES
CATALYZED SYNTHESIS
ENZYME IMMOBILIZATION
BIOBASED POLYESTERS
AROMATIC POLYESTERS
POLYMERIC MATERIALS
BUILDING-BLOCK
IONIC LIQUIDS
Antarc*
Antarctica
Online Access:https://hdl.handle.net/11370/81af2cbf-3313-46ca-ad84-0d21d099b6f9
https://research.rug.nl/en/publications/81af2cbf-3313-46ca-ad84-0d21d099b6f9
https://doi.org/10.1039/c5py00629e
https://pure.rug.nl/ws/files/82943060/A_biocatalytic_approach_towards_sustainable_furanic_aliphatic_polyesters.pdf
Description
Summary:An eco-friendly approach towards furanic-aliphatic polyesters as sustainable alternatives to aromatic-aliphatic polyesters is presented. In this approach, biobased dimethyl 2,5-furandicarboxylate (DMFDCA) is polymerized with various (potentially) renewable aliphatic diols via Candida antarctica Lipase B (CALB)-catalyzed polymerization using a two-stage method in diphenyl ether. A series of furanic-aliphatic polyesters and oligoesters is successfully produced via enzymatic polymerization. Some products reach very high (M-w) over bar (weight average molecular weight) values of around 100 000 g mol(-1). Studies on the effect of the diol structure on the enzymatic polymerization indicate that CALB prefers long-chain alkane-alpha,omega-aliphatic linear diols containing more than 3 carbons. We also found that the molecular weights of the obtained furanic-aliphatic polyesters increase steadily with the increase of reaction temperature from 80 to 140 degrees C. MALDI-ToF MS analysis reveals that five polyester species may be present in the final products. They were terminated with the ester/-OH, ester/ester, -OH/-OH, no end groups (cyclic), and ester/aldehyde groups, respectively. Furthermore, the structure-property relationships were studied by comparing the crystalline/thermal properties of a series of relevant furanic-aliphatic polyesters.

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