Palaeoceanography of the holocene and late-glacial N.E. Atlantic: development and application of biomarker proxies of environmental change
The aim of this thesis is to develop and apply novel climate proxies to understand the palaeoceanographic evolution of the N.E. Atlantic during the late-Glacial and Holocene. The proxies investigated are based on organic molecular compounds called lipid biomarkers and bulk organic matter properties....
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| Format: | Thesis |
| Language: | unknown |
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2003
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| Online Access: | http://etheses.dur.ac.uk/4019/ http://etheses.dur.ac.uk/4019/1/4019_1536.pdf |
| Summary: | The aim of this thesis is to develop and apply novel climate proxies to understand the palaeoceanographic evolution of the N.E. Atlantic during the late-Glacial and Holocene. The proxies investigated are based on organic molecular compounds called lipid biomarkers and bulk organic matter properties. The primary focus is on long-chain alkenones, molecules which have been extensively used in mid and low latitude open oceans to reconstruct sea surface temperatures (SSTs) during the Quaternary. Thus, the relative abundance of some alkenones is related to the growth temperature of the algae at the time of the biosynthesis of these molecules (expressed in the U(^K)(_37) and U(^K)(_37)’ indices). In high latitudes and coastal environments, the temperature dependence of alkenones is controversial, and the potential environmental information from alkenones is not yet well understood. In such locations there is increasing abundance of the C(_37:4) alkenone (quantified as %C(_37:4)). The presence of this component has been related to changes in the relative budget of freshwater in the surface ocean. A central aim of this thesis is to carry out an empirical investigation to find out the key environmental factors that control %C(_37:4) to assess its potential as a palaeoceanographic proxy. Research was conducted in the Nordic Seas and N.W. Scotland using samples from the water column, surficial sediment and sediment cores. The research undertaken can be broken down in three main sections: Alkenone distributions in the Nordic Seas. The aim was to clarify and extend the application of alkenones as palaeoceanographic proxies in subpolar to polar environments. Samples of filtered sea surface POM were analysed and extremely high %C(_37:4) values (up to 77%) were measured in polar waters (up to 80% sea-ice cover). Values of %C(_37:4) across the Nordic Seas showed a strong association with water mass type. A combined data-set revealed a stronger correlation of %C(_37:4) to sea surface salinity' (SSS, R(^2) = 0.72) than to SST ... |
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