Meteoric water contribution to sea ice formation and its control of the surfacewater carbonate cycle on the Wandel Sea shelf, northeastern Greenland

An influx of glacial meltwater has the ability to alter the properties of marine surface waters and their ability to exchange CO 2 through changes to water column stratification and the inorganic carbon system. Here, we report how inputs of meteoric water affect the physical and biogeochemical prope...

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Bibliographic Details
Published in:Elementa: Science of the Anthropocene
Main Authors: Geilfus, Nicolas Xavier, Munson, Kathleen, Lemes, Marcos, Wang, Feiyue, Tison, Jean Louis, Rysgaard, Søren
Format: Article in Journal/Newspaper
Language:English
Published: 2021
Subjects:
CO
Online Access:https://pure.au.dk/portal/da/publications/meteoric-water-contribution-to-sea-ice-formation-and-its-control-of-the-surfacewater-carbonate-cycle-on-the-wandel-sea-shelf-northeastern-greenland(c9145001-12e4-4612-9224-ac49aaef07a4).html
https://doi.org/10.1525/elementa.2021.00004
http://www.scopus.com/inward/record.url?scp=85121205706&partnerID=8YFLogxK
Description
Summary:An influx of glacial meltwater has the ability to alter the properties of marine surface waters and their ability to exchange CO 2 through changes to water column stratification and the inorganic carbon system. Here, we report how inputs of meteoric water affect the physical and biogeochemical properties of both the water column and the sea ice cover on the Wandel Sea shelf, northeastern Greenland, during spring 2015. The observed depleted δ 18 O-H 2 O in the water column, with surface water values as low as -16.3 %, suggests a strong input of meteoric water (i.e., water derived from atmospheric precipitation). Depleted δ 18 O-H 2 O observed within sea ice (from -21.5 to -8.0%) reflects its formation from surface water that was already depleted isotopically. In addition, a thick snow cover, as present during the study, promotes the formation of snow ice as well as insulates the ice cover. Within sea ice, the resulting relatively warm temperature and low salinity impedes ikaite formation. However, measurements of total dissolved inorganic carbon and total alkalinity indicate that, in both sea ice and the water column, the dissolution of calcium carbonate was the main process affecting the carbonate system. This finding suggests that inputs of glacial meltwater deliver glacier-derived carbonate minerals to the ocean which become incorporated within the ice structure, increasing calcium carbonate dissolution in the water column in the absence of ikaite precipitation within the sea ice. If widespread in glacial-fed waters, bedrock carbonate minerals could increase CO 2 sequestration in glacial catchments despite the weakening of the sea ice carbon pump.