| Summary: | Climate warming can impact arctic ecosystems by altering watershed geochemistry through permafrost degradation and increased mineral weathering. This dissertation evaluated the importance of these changes in arctic Alaska by examining permafrost and soil geochemistry, mineral weathering, and changes in stream geochemistry. Elemental and 87 Sr/ 86 Sr geochemistry of streams and soils, permafrost, and soil parent materials from glacial deposit surfaces of varying ages were evaluated. Carbonate content increases with soil depth across all surfaces, and exchangeable P, K, and Ca concentrations are significantly (p<0.05) greater in permafrost than in active-layer mineral soil. These results suggest that increasing thaw depth will increase carbonate alkalinity, Ca, K, and P supply to soils and streams across the region. Elemental depletion factors for a subset of these soils forming a chronosequence indicate that carbonate weathering is the dominant weathering process, and long-term weathering rates are 0.5-11 meq m -2 yr -2 . Based on increasing Ca/Na and Ca/Ba and decreasing 87 Sr/ 86 Sr with depth in soils and permafrost, elemental ratios and 87 Sr/ 86 Sr in an arctic stream were used as tracers of the maximum depth of soil water flow and therefore changes in integrated thaw depth across the watershed. From 1994 to 2004, mean 87 Sr/ 86 Sr values in low-discharge late summer stream water decreased from 0.7122 to 0.7119 (R 2 =0.62, p=0.012), and Ca/Na and Ca/Ba showed significant increasing trends that were consistent with increasing depth of soil water flowpaths. These trends provide new evidence for increasing thaw depth, despite the lack of measured increases using traditional thaw probe techniques. The effects of an in-stream thermokarst feature on stream chemistry were also investigated. Solute concentrations, alkalinity, and conductivity were elevated downstream from the thermokarst. Estimates suggest geochemical changes may be detectable downstream in rivers up to 100 times the size of the original affected ...
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