Ikaite pseudomorphs in Neoproterozoic Dalradian slates record Earth’s coldest metamorphism

Calcite pseudomorphs have replaced euhedral ikaite (CaCO3.6H2O)porphyroblasts in Dalradian calcareous slates and metadolostones of western Scotland, with a volume decrease of at least 47%. Porphyroblast-fabric relationships indicate that the initial growth of ikaite post-dates a penetrative tectoni...

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Bibliographic Details
Published in:Journal of the Geological Society
Main Authors: Dempster, Tim, Jess, Scott A.
Format: Article in Journal/Newspaper
Language:English
Published: Geological Society of London 2015
Subjects:
Online Access:http://eprints.gla.ac.uk/104777/
http://eprints.gla.ac.uk/104777/1/104777.pdf
Description
Summary:Calcite pseudomorphs have replaced euhedral ikaite (CaCO3.6H2O)porphyroblasts in Dalradian calcareous slates and metadolostones of western Scotland, with a volume decrease of at least 47%. Porphyroblast-fabric relationships indicate that the initial growth of ikaite post-dates a penetrative tectonic fabric developed during upright folding. This is the first reported occurrence of metamorphic ikaite porphyroblasts and points towards growth within the slates during an ultra-low temperature metamorphism with an exceptionally low geothermal gradient. This event is associated with the penetration of long-lived and extreme permafrost deep into sub aerially exposed bedrock during Neoproterozoic glaciation. The presence of the well preserved pseudomorphs within the Easdale slates of the Argyll group implies that a Neoproterozoic orogenic unconformity exists above the stratigraphic position of theserocks.