Standardization for oxygen isotope ratio measurement - still an unsolved problem

Numerous organic and inorganic laboratory standards were gathered from nine European and North American laboratories and were analyzed for their δ18O values with a new on-line high temperature pyrolysis system that was calibrated using Vienna standard mean ocean water (VSMOW) and standard light Anta...

Full description

Bibliographic Details
Main Authors: Kornexl, B.E., Werner, R.A., Gehre, Matthias
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 1999
Subjects:
Online Access:https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=8131
https://doi.org/10.1002/(SICI)1097-0231(19990715)13:13<1248::AID-RCM560>3.0.CO;2-H
Description
Summary:Numerous organic and inorganic laboratory standards were gathered from nine European and North American laboratories and were analyzed for their δ18O values with a new on-line high temperature pyrolysis system that was calibrated using Vienna standard mean ocean water (VSMOW) and standard light Antartic precipitation (SLAP) internationally distributed reference water samples. Especially for organic materials, discrepancies between reported and measured values were high, ranging up to 2‰. The reasons for these discrepancies are discussed and the need for an exact and reliable calibration of existing reference materials, as well as for the establishment of additional organic and inorganic reference materials is stressed.