| Summary: | Graduate cbkusel@yahoo.ca Developing critical loads for nitrogen (N) in the Athabasca Oil Sands Region (AOSR) requires an understanding of the hydrological connectivity and potential for N transport among uplands, fens and bogs typical in the wetland-rich Boreal region of northern Alberta. The Cumulative Environmental Management Association’s (CEMA) overarching mandate is to determine a nitrogen critical load specific to the Boreal region of northern Alberta. To this end, nitrogen amendment experiments were initiated at two Boreal wetland sites: an upland – rich fen gradient at Jack Pine High (JPH) and an upland – fen – bog mosaic at Mariana Lakes (ML), 45 km north and 100 km south of Fort McMurray respectively. The objectives of this study are to use geochemical and isotopic tracers to describe baseline hydrogeochemical variability and connectivity between bog, fens and upland areas in the AOSR. Sites were instrumented with piezometer nests and water table wells along transects that cover the targeted landscape units (n = 108 sampling locations). Fieldwork related to this thesis was conducted during the open-water season: in June and August 2011, and in May, July, and September 2012. Field campaigns also included a snow survey (March 2012), and spring melt/freshet sampling (April 2012). The analysis of spatiotemporal variability of water isotopes and geochemistry in the years 2011-2012 yielded: i) a characterization of baseline conditions from which perturbations can be assessed, and ii) evidence of connectivity among landscape units. No evidence for elevated concentrations of nitrogen related to the amendment experiments was found in 2011 or 2012. The baseline characterization and annual monitoring did show increasing concentrations of inorganic ammonium with increasing depth associated with increasing solute concentrations: average concentrations of inorganic ammonium were 23 mg/L at deepest sampling locations (7 m) at ML bog and ML fen landscape units. These ammonium concentrations in porewaters, given a ...
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