Mesoscale modulation of air-sea CO2 flux in Drake Passage

We investigate the role of mesoscale eddies in modulating air-sea CO2 flux and associated biogeochemical fields in Drake Passage using in situ observations and an eddy-resolving numerical model. Both observations and model show a negative correlation between temperature and partial pressure of CO2 (...

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Bibliographic Details
Published in:Journal of Geophysical Research: Oceans
Main Authors: Song, Hajoon, Marshall, John, Munro, David R., Dutkiewicz, Stephanie, Sweeney, Colm, Mcgillicuddy, D. J., Jr., Hausmann, Ute
Format: Text
Language:English
Published: Amer Geophysical Union
Subjects:
geo
Online Access:https://doi.org/10.1002/2016JC011714
https://archimer.ifremer.fr/doc/00383/49407/49894.pdf
https://archimer.ifremer.fr/doc/00383/49407/
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Summary:We investigate the role of mesoscale eddies in modulating air-sea CO2 flux and associated biogeochemical fields in Drake Passage using in situ observations and an eddy-resolving numerical model. Both observations and model show a negative correlation between temperature and partial pressure of CO2 (pCO(2)) anomalies at the sea surface in austral summer, indicating that warm/cold anticyclonic/cyclonic eddies take up more/less CO2. In austral winter, in contrast, relationships are reversed: warm/cold anticyclonic/cyclonic eddies are characterized by a positive/negative pCO(2) anomaly and more/less CO2 outgassing. It is argued that DIC-driven effects on pCO(2) are greater than temperature effects in austral summer, leading to a negative correlation. In austral winter, however, the reverse is true. An eddy-centric analysis of the model solution reveals that nitrate and iron respond differently to the same vertical mixing: vertical mixing has a greater impact on iron because its normalized vertical gradient at the base of the surface mixed layer is an order of magnitude greater than that of nitrate.