A Counter-Current Heat-Exchange Reactor for the Thermal Stimulation of Hydrate-Bearing Sediments

Since huge amounts of CH 4 are bound in natural gas hydrates occurring at active and passive continental margins and in permafrost regions, the production of natural gas from hydrate-bearing sediments has become of more and more interest. Three different methods to destabilize hydrates and release t...

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Bibliographic Details
Main Authors: Judith M. Schicks, Erik Spangenberg, Ronny Giese, Manja Luzi-Helbing, Mike Priegnitz, Bettina Beeskow-Strauch
Format: Article in Journal/Newspaper
Language:unknown
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Online Access:https://www.mdpi.com/1996-1073/6/6/3002/pdf
https://www.mdpi.com/1996-1073/6/6/3002/
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Summary:Since huge amounts of CH 4 are bound in natural gas hydrates occurring at active and passive continental margins and in permafrost regions, the production of natural gas from hydrate-bearing sediments has become of more and more interest. Three different methods to destabilize hydrates and release the CH 4 gas are discussed in principle: thermal stimulation, depressurization and chemical stimulation. This study focusses on the thermal stimulation using a counter-current heat-exchange reactor for the in situ combustion of CH 4 . The principle of in situ combustion as a method for thermal stimulation of hydrate bearing sediments has been introduced and discussed earlier [1,2]. In this study we present the first results of several tests performed in a pilot plant scale using a counter-current heat-exchange reactor. The heat of the flameless, catalytic oxidation of CH 4 was used for the decomposition of hydrates in sand within a LArge Reservoir Simulator (LARS). Different catalysts were tested, varying from diverse elements of the platinum group to a universal metal catalyst. The results show differences regarding the conversion rate of CH 4 to CO 2 . The promising results of the latest reactor test, for which LARS was filled with sand and ca. 80% of the pore space was saturated with CH 4 hydrate, are also presented in this study. The data analysis showed that about 15% of the CH 4 gas released from hydrates would have to be used for the successful dissociation of all hydrates in the sediment using thermal stimulation via in situ combustion. thermal stimulation; in situ combustion; gas production; counter-current heat-exchange reactor