Molecular scale evidence of new particle formation via sequential addition of HIO3

• Published in: Nature
• Main Authors: Sipilä, Mikko, Sarnela, Nina, Jokinen, Tuija, Henschel, Henning, Junninen, Heikki, Kontkanen, Jenni, Richters, Stefanie, Kangasluoma, Juha, Franchin, Alessandro, Peräkylä, Otso, Rissanen, Matti P., Ehn, Mikael, Vehkamäki, Hanna, Kurten, Theo, Berndt, Torsten, Petäjä, Tuukka, Worsnop, Douglas, Ceburnis, Darius, Kerminen, Veli-Matti, Kulmala, Markku, O’Dowd, Colin
• Format: Text
• Language: English
• Published: 2016
• Subjects: Article; Greenland; Mace; Queen Maud Land; Antarc*; Antarctica
• Online Access: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5136290/; http://www.ncbi.nlm.nih.gov/pubmed/27580030; https://doi.org/10.1038/nature19314

Homogeneous nucleation and subsequent cluster growth leads to the formation of new aerosol particles in the atmosphere1. Nucleation of sulphuric acid and organic vapours is thought to be responsible for new particle formation over continents1,2 while iodine oxide vapours have been implicated in particle formation over coastal regions3–7. Molecular clustering pathways involved in atmospheric particle formation have been elucidated in controlled laboratory studies of chemically simple systems2,8–10. But no direct molecular-level observations of nucleation in atmospheric field conditions involving either sulphuric acid, organic or iodine oxide vapours have been reported to date11. Here we report field data from Mace Head, Ireland and supporting data from northern Greenland and Queen Maud Land, Antarctica that allow for the identification of the molecular steps involved in new particle formation in an iodine-rich, coastal atmospheric environment. We find that the formation and initial growth process is almost exclusively driven by iodine oxoacids and iodine oxide vapours with average resulting cluster O:I ratios of 2.4. Based on the high O:I ratio, together with observed high concentrations of iodic acid, HIO3, we suggest that cluster formation primarily proceeds by sequential addition of iodic acid HIO3, followed by intra-cluster restructuring to I2O5 and recycling of water in the atmosphere or upon drying. Overall, our study provides ambient atmospheric molecular-level observations of nucleation, supporting the previously suggested role of iodine containing species in new particle formation3–7, 12–18, and identifies the key nucleating compound.