Significant contribution of dissolved organic matter to seawater alkalinity

The present study shows a previously undocumented role of dissolved organic matter in the marine carbonate system. During photosynthesis, phytoplankton release dissolved organic compounds containing basic functional groups that readily react with protons during seawater titration, and thereby contri...

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Bibliographic Details
Published in:Geophysical Research Letters
Main Authors: Kim, HC, Lee, K
Other Authors: 환경공학부, 10056383
Format: Article in Journal/Newspaper
Language:English
Published: AMER GEOPHYSICAL UNION 2009
Subjects:
PH
Online Access:https://oasis.postech.ac.kr/handle/2014.oak/27799
https://doi.org/10.1029/2009GL040271
Description
Summary:The present study shows a previously undocumented role of dissolved organic matter in the marine carbonate system. During photosynthesis, phytoplankton release dissolved organic compounds containing basic functional groups that readily react with protons during seawater titration, and thereby contribute to alkalinity (a measure of buffering capacity). The magnitude of the contribution of dissolved organic compounds to seawater alkalinity is species dependent, suggesting that individual phytoplankton species exude dissolved organic compounds with unique proton accepting capacities. Our study shows that dissolved organic matter produced by marine phytoplankton during photosynthesis is a newly identified buffering component in the ocean, and indicates that the contribution of dissolved organic matter to seawater alkalinity can be significant in the biologically productive upper ocean, where to date it has been unrecognized or considered insignificant. Citation: Kim, H.-C., and K. Lee (2009), Significant contribution of dissolved organic matter to seawater alkalinity, Geophys. Res. Lett., 36, L20603, doi:10.1029/2009GL040271. X 1 1 45 47 scie scopus