Atmospheric carbonyl sulfide sources from anthropogenic activity: Implications for carbon cycle constraints
Carbonyl sulfide (COS) has recently emerged as an atmospheric tracer of gross primary production. All modeling studies of COS air-monitoring data rely on a climatological anthropogenic inventory that does not reflect present conditions or support interpretation of ice core and firn trends. Here we d...
| Published in: | Geophysical Research Letters |
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| Main Authors: | , , , , , |
| Language: | unknown |
| Published: |
2022
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| Subjects: | |
| Online Access: | http://www.osti.gov/servlets/purl/1208712 https://www.osti.gov/biblio/1208712 https://doi.org/10.1002/2015GL063445 |
| Summary: | Carbonyl sulfide (COS) has recently emerged as an atmospheric tracer of gross primary production. All modeling studies of COS air-monitoring data rely on a climatological anthropogenic inventory that does not reflect present conditions or support interpretation of ice core and firn trends. Here we develop a global anthropogenic inventory for the years 1850 to 2013 based on new emission measurements and material-specific data. By applying methods from a recent regional inventory to global data, we find that the anthropogenic source is similar in magnitude to the plant sink, confounding carbon cycle applications. However, a material-specific approach results in a current anthropogenic source that is only one third of plant uptake and is concentrated in Asia, supporting carbon cycle applications of global air-monitoring data. As a result, changes in the anthropogenic source alone cannot explain the century-scale mixing ratio growth, which suggests that ice and firn data may provide the first global history of gross primary production. |
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