FILM FORMATION ON LITHIUM IN PROPYLENE CARBONATE SOLUTIONS UNDER OPEN CIRCUIT CONDITIONS
The nature of protective surface layers formed on lithium in propylene carbonate solutions of LiClO{sub 4} and LiAsF{sub 6} at open circuit has been investigated by electrochemical pulse measurements. The results are consistent with the fastformation of a compact thin layer resulting from the reacti...
| Main Authors: | , , |
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| Language: | unknown |
| Published: |
2011
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| Subjects: | |
| Online Access: | http://www.osti.gov/servlets/purl/1022096 https://www.osti.gov/biblio/1022096 |
| Summary: | The nature of protective surface layers formed on lithium in propylene carbonate solutions of LiClO{sub 4} and LiAsF{sub 6} at open circuit has been investigated by electrochemical pulse measurements. The results are consistent with the fastformation of a compact thin layer resulting from the reaction with residual water. This layer acts as a solid ionicconductor. Slow corrosion or decomposition processes produce a thicker porous overlayer. |
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