Geochemistry of surficial and ice-rafted sediments from the Laptev Sea (Siberia)

The Laptev Sea, as a part of the world’s widest continental shelves surrounding the Arctic Ocean, is a key area for understanding the land–ocean interaction in high latitude regions. With a yearly freshwater input of 511 km3, the Lena River—one of the eight major world rivers—has an influencing cont...

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Bibliographic Details
Published in:Estuarine, Coastal and Shelf Science
Main Authors: Hölemann, Jens A., Schirmacher, Martina, Kassens, Heidemarie, Prange, Andreas
Format: Article in Journal/Newspaper
Language:English
Published: Elsevier 1999
Subjects:
Online Access:https://oceanrep.geomar.de/id/eprint/26926/
https://oceanrep.geomar.de/id/eprint/26926/1/1999_Hoelemann-etal-Geochemistry_ECSS-49.pdf
https://doi.org/10.1006/ecss.1999.0485
Description
Summary:The Laptev Sea, as a part of the world’s widest continental shelves surrounding the Arctic Ocean, is a key area for understanding the land–ocean interaction in high latitude regions. With a yearly freshwater input of 511 km3, the Lena River—one of the eight major world rivers—has an influencing control over the environment of this Arctic marginal sea, which is ice-covered during most of the year. In this paper, the first measurements are presented of the major and trace element distribution within the <20 μm grain size fraction of surficial sediments and of particulate matter in new and young ice from the Laptev Sea (Siberian Arctic). The concentration and distribution of major and trace elements have been determined in 51 surficial sediment samples covering the whole Laptev Sea shelf south of the 50 m isobath. Thirty-one samples of particulate matter in newly formed ice were taken during the freeze-up period in 1995. Median concentration levels of heavy metals in surficial sediments (Ni (46 μg g−1), Cu (26 μg g−1), Zn (111 μg g−1) and Pb (21 μg g−1) are within the concentration range of marine unpolluted sediments. Also the sediment-laden ice showed no indication of anthropogenic perturbation of the trace metal inventory. Spatial distribution patterns of heavy metals are mainly determined by variation of mineral composition and different fluvial sediment sources in the eastern and western Laptev Sea. The Laptev Sea shelf is cut by five north–south trending submarine valleys. Enrichment of manganese in the oxic surficial sediment layer within these valleys and the occurrence of small ferromanganese nodules are caused by a high input of dissolved and particulate Mn from the Lena River and a strong diagenetic cycling of Mn on the Laptev Sea shelf. Evidence is given that the content of As in surficial sediments is also strongly affected by diagenetic cycling. This causes surficial sediment As concentrations of more than 100 μg g−1. Enrichment of Mn and As was mainly observed in the submarine valleys distant from ...