Sulfur isotope signatures of sulfides from the Khibina and Lovozero massifs (Kola Alkaline Province, Fennoscandian Shield)

The sulfur isotope geochemistry of the Khibina and Lovozero agpaitic massifs provides an opportunity to understand the role of plume-lithosphere interaction processes responsible for the Paleozoic alkaline igneous activity in the north-eastern part of the Fennoscandian Shield. The stable sulfur isot...

Full description

Bibliographic Details
Main Authors: Huber, M., Mokrushin, A. V.
Format: Other Non-Article Part of Journal/Newspaper
Language:English
Published: 2021
Subjects:
Online Access:http://hdl.handle.net/1834/41686
Description
Summary:The sulfur isotope geochemistry of the Khibina and Lovozero agpaitic massifs provides an opportunity to understand the role of plume-lithosphere interaction processes responsible for the Paleozoic alkaline igneous activity in the north-eastern part of the Fennoscandian Shield. The stable sulfur isotope δ 34S analysis using triple collector isotope ratio mass spectrometer (IRMS) has been carried out on the pentlandite, chalcopyrite and pyrite from nepheline syenites. The δ 34S values for pentlandite from Khibina rocks range from +0.69 to +2.06 ‰ relative to the Vienna Canyon Diablo Troillite standard (VCDT), and the pyrite has significantly higher δ 34S values up to +4.92 ‰ VCDT. The pentlandite from the Lovozero samples has value +1.48 ‰ VCDT, δ 34S values of chalcopyrite is +2.85 ‰ VCDT. The maximum positive δ 34S values are obtained for Lovozero pyrite, which vary from +5.41 to +6.30 ‰ VCDT. Comparison of sulfur-geochemical features of Khibina and Lovozero nepheline syenite with δ 34S data for the carbonatites from the Khibina, Sallanlatvi, Seblyavr, Vuoriyarvi, Salmagora and Kovdor massifs show later carbonatite formation relatively to associated alkaline rocks. Geochemical sulfur isotope δ 34S investigations emphasizes that parental magmas of the Khibina and Lovozero alkaline massifs were derived from a metasomatized subcontinental lithospheric mantle (SCLM). We suggest that high-?34S signature on the SCLM (δ 34S of +1 to +6 ‰ VCDT) can be explained by subduction of the high-δ 34S Archaean crust. Геохимия изотопов серы Хибинского и Ловозерского агпаитовых массивов дает возможность понять роль плюм-литосферных процессов, ответственных за палеозойскую щелочную магматическую активность в северо-восточной части Фенноскандинавского щита. Изотопный состав серы (δ 34S) получен для пентландита, халькопирита и пирита из нефелиновых сиенитов с использованием масс-спектрометра с тройным коллектором (IRMS). Значения δ 34S пентландита из пород Хибинского массива варьируют от +0,69 до +2,06 ‰ относительно стандарта ...