Formaldehyde (HCHO) in air, snow, and interstitial air at Concordia (East Antarctic Plateau) in summer

• Published in: Atmospheric Chemistry and Physics
• Main Authors: Preunkert, S., Legrand, M., Frey, M. M., Kukui, A., Savarino, J., Gallée, H., King, M., Jourdain, B., Vicars, W., Helmig, D.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2015
• Subjects: article; Verlagsveröffentlichung; Antarctic; Austral; Antarc*
• Online Access: https://doi.org/10.5194/acp-15-6689-2015; https://noa.gwlb.de/receive/cop_mods_00044346; https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00043966/acp-15-6689-2015.pdf; https://acp.copernicus.org/articles/15/6689/2015/acp-15-6689-2015.pdf

During the 2011/12 and 2012/13 austral summers, HCHO was investigated for the first time in ambient air, snow, and interstitial air at the Concordia site, located near Dome C on the East Antarctic Plateau, by deploying an Aerolaser AL-4021 analyzer. Snow emission fluxes were estimated from vertical gradients of mixing ratios observed at 1 cm and 1 m above the snow surface as well as in interstitial air a few centimeters below the surface and in air just above the snowpack. Typical flux values range between 1 and 2 × 1012 molecules m−2 s−1 at night and 3 and 5 × 1012 molecules m−2 s−1 at noon. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible compared to temperature-driven air–snow exchanges. At 1 m above the snow surface, the observed mean mixing ratio of 130 pptv and its diurnal cycle characterized by a slight decrease around noon are quite well reproduced by 1-D simulations that include snow emissions and gas-phase methane oxidation chemistry. Simulations indicate that the gas-phase production from CH4 oxidation largely contributes (66%) to the observed HCHO mixing ratios. In addition, HCHO snow emissions account for ~ 30% at night and ~ 10% at noon to the observed HCHO levels.