Chemistry of OClO in the Antarctic stratosphere - Implications for bromine

Previous observations of OClO over the Antarctic obtained in 1986 are used to constrain the stratospheric abundance of bromine. The observed diurnal variation is consistent with the production of OClO via the reaction of ClO with BrO if the branching ratio to the BrCl channel is between 3.5 and 14 p...

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Bibliographic Details
Main Authors: Salawitch, Ross J., Wofsy, Steven C., Mcelroy, Michael B.
Format: Other/Unknown Material
Language:unknown
Published: 1988
Subjects:
45
Antarctic
The Antarctic
Antarc*
Online Access:http://ntrs.nasa.gov/search.jsp?R=19880045246
Description
Summary:Previous observations of OClO over the Antarctic obtained in 1986 are used to constrain the stratospheric abundance of bromine. The observed diurnal variation is consistent with the production of OClO via the reaction of ClO with BrO if the branching ratio to the BrCl channel is between 3.5 and 14 percent. Otherwise, an additional source in twilight is indicated. The present results suggest a stratospheric bromine concentration of 16 + or - 4 pptv, a value which is consistent with independent measurements.

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