Glauconite Formation in Late Eocene ODP Site 696 Sediment in West Antarctica

Antarctic sediment cores collected during Leg 113 of the Ocean Drilling Program (ODP) provide important paleoclimatic evidence over the Eocene-Oligocene transition (EOT) – a period of global cooling from greenhouse to icehouse approximately 34 million years ago. The cores, collected thirty years ago...

Full description

Bibliographic Details
Main Author: States, Abbey
Format: Text
Language:unknown
Published: Montclair State University Digital Commons 2019
Subjects:
Online Access:https://digitalcommons.montclair.edu/etd/221
https://digitalcommons.montclair.edu/context/etd/article/1221/viewcontent/States__Abbey_Redacted.pdf
Description
Summary:Antarctic sediment cores collected during Leg 113 of the Ocean Drilling Program (ODP) provide important paleoclimatic evidence over the Eocene-Oligocene transition (EOT) – a period of global cooling from greenhouse to icehouse approximately 34 million years ago. The cores, collected thirty years ago, offer new research opportunities with the application of an updated age model for the EOT in West Antarctica (Houben et al., 2013). The core from ODP Site 696 in the Weddell Sea contains a complete EOT record, with a remarkably green stratum attributed to glauconite dated to the late Eocene. The sediment composition, clay mineralogy, and geochemistry of this interval was investigated in the context of recent particle size data and an improved age model. Smear slide and X-ray diffraction analyses confirm the green mineral is an authigenic, incipient form of glauconite with a minor contribution of expandable montmorillonite to the clay fraction. Major and trace element analysis show deposition occurred under reducing, suboxic conditions with low detrital input for samples with a high fraction of glauconite. Alteration of illite by Fe2+ substitution is the likely formation mechanism, possibly catalyzed by an increase in oceanic productivity. The highest-glauconite sediment interval, dated to ~34.5-35 mya, suggests a marine transgression peak in the South Orkney Microcontinent region during this time caused by crustal subsidence prior to the onset of full continental glaciation. These results document early effects of ice sheet advance in the Weddell Sea, though more research is needed to determine whether the impacts are caused by glaciation from East or West Antarctica.