Mass-independent isotopic compositions in terrestrial and extraterrestrial solids and their applications

In 1983, Thiemens and Heidenreich reported the first chemically produced mass-independent isotope effect. This work has been shown to have a wide range of applications, including atmospheric chemistry, solar system evolution, and chemical physics. This work has recently been reviewed (Weston, R. E....

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Bibliographic Details
Published in:Accounts of Chemical Research
Main Authors: Thiemens, M. H., Savarino, J., Farquhar, J., Bao, H.
Format: Text
Language:unknown
Published: LSU Scholarly Repository 2001
Subjects:
Online Access:https://repository.lsu.edu/geo_pubs/96
https://doi.org/10.1021/ar960224f
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Summary:In 1983, Thiemens and Heidenreich reported the first chemically produced mass-independent isotope effect. This work has been shown to have a wide range of applications, including atmospheric chemistry, solar system evolution, and chemical physics. This work has recently been reviewed (Weston, R. E. Chem. Rev. 1999, 99, 2115-2136; Thiemens, M. H. Science 1999, 283, 341-345). In this Account, observations of mass-independent isotopic compositions in terrestrial and Martian solids are reviewed. A wide range of applications, including formation and transport of aerosols in the present atmosphere, chemistry of ancient atmospheres and oceans, history and coupling of the atmosphere-surface in the Antarctic dry valleys, origin and evolution of oxygen in the Earth's earliest environment, and the chemistry of the atmosphere and surface of Mars, are discussed.