TransCom N2O model inter-comparison – Part 1: Assessing the influence of transport and surface fluxes on tropospheric N2O variability

• Published in: Atmospheric Chemistry and Physics
• Main Authors: Thompson, RL, Patra, PK, Ishijima, K, Saikawa, E, Corazza, M, Karstens, U, Wilson, C, Bergamaschi, P, Dlugokencky, E, Sweeney, C, Prinn, RG, Weiss, RF, O'Doherty, S, Fraser, PJ, Steele, LP, Krummel, PB, Saunois, M, Chipperfield, M, Bousquet, P
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2014
• Subjects: Southern Ocean
• Online Access: https://eprints.whiterose.ac.uk/80028/; https://eprints.whiterose.ac.uk/80028/1/TransCom%20NO%20model%20inter-comparison-Part%201%20Assessing%20the%20influence%20of%20transport%20and%20surface%20fluxes%20on%20tropospheric%20NO%20variability.pdf; https://doi.org/10.5194/acp-14-4349-2014

We present a comparison of chemistry-transport models (TransCom-N O) to examine the importance of atmospheric transport and surface fluxes on the variability of NO mixing ratios in the troposphere. Six different models and two model variants participated in the inter-comparison and simulations were made for the period 2006 to 2009. In addition to N O, simulations of CFC-12 and SF6 were made by a subset of four of the models to provide information on the models' proficiency in stratosphere-troposphere exchange (STE) and meridional transport, respectively. The same prior emissions were used by all models to restrict differences among models to transport and chemistry alone. Four different NO flux scenarios totalling between 14 and 17 TgN yr (for 2005) globally were also compared. The modelled NO mixing ratios were assessed against observations from in situ stations, discrete air sampling networks and aircraft. All models adequately captured the large-scale patterns of N O and the vertical gradient from the troposphere to the stratosphere and most models also adequately captured the NO tropospheric growth rate. However, all models underestimated the inter-hemispheric NO gradient by at least 0.33 parts per billion (ppb), equivalent to 1.5 TgN, which, even after accounting for an overestimate of emissions in the Southern Ocean of circa 1.0 TgN, points to a likely underestimate of the Northern Hemisphere source by up to 0.5 TgN and/or an overestimate of STE in the Northern Hemisphere. Comparison with aircraft data reveal that the models overestimate the amplitude of the NO seasonal cycle at Hawaii (21° N, 158° W) below circa 6000 m, suggesting an overestimate of the importance of stratosphere to troposphere transport in the lower troposphere at this latitude. In the Northern Hemisphere, most of the models that provided CFC-12 simulations captured the phase of the CFC-12, seasonal cycle, indicating a reasonable representation of the timing of STE. However, for NO all models simulated a too early minimum by 2 to 3 ...