Chemical fractionation in sea ice and glacier ice

Analyses of SO^<2->_4, Na^+,Cl^-,Mg^<2+> and Ca^<2+>in ice core samples of multiyear sea ice in the Fram Strait show strong correlations between the concentrations of Mg^<2+>,Na^+,Cl^- and Ca^<2+>(r=0・99)while the correlation coefficients between these ions and SO^<2...

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Main Authors: GJESSING, Yngvar, HANSSEN-BAUER, Inger, FUJII, Yoshiyuki, KAMEDA, Takao, KAMIYAMA, Kokichi, KAWAMURA, Toshiyuki
Language:English
Published: 日本雪氷学会
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Online Access:https://kitami-it.repo.nii.ac.jp/record/7179/files/5114.pdf
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Summary:Analyses of SO^<2->_4, Na^+,Cl^-,Mg^<2+> and Ca^<2+>in ice core samples of multiyear sea ice in the Fram Strait show strong correlations between the concentrations of Mg^<2+>,Na^+,Cl^- and Ca^<2+>(r=0・99)while the correlation coefficients between these ions and SO^<2->_4 were less than O.9.Most samples had a deficit of sulfate relative to sea water of the same salinity. Excess sulfate was found in a few samples with low salinities.Chemical analyses of snow,ice and meltwater from temperate glaciers have demonstrated that sulfate is more efficiently washed out when meltwater penetrates through ice than are Cl^?,Mg^<2+> and Ca^<2+>.Washout therefore leads to deficit of sulfate in ice,whereas refreezing of meltwater creates an excess of sulfate relative to sea water with the same content of chloride. application/pdf journal article