[Mn(co)(3)(bpy)(n-2-chlorobenzylbenzimidazole)] otf complex as a new photoactivatable co-releasing molecule

Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OT...

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Bibliographic Details
Main Authors: Ustun, E., Dusunceli, S. Demir, Ozdemir, I.
Other Authors: İnönü Üniversitesi
Format: Article in Journal/Newspaper
Language:English
Published: Bulgarıan acad scıence, central lıbrary 7 noemvrı no 1, sofıa, 00000, bulgarıa 2017
Subjects:
Group-6 metal-carbonyls
manganese complexes
trıcarbonyl complexes
antıoxıdant actıvıty
dft calculatıon
monoxıde
electrochemıstry
therapy
lıgands
desıgn
Orca
Online Access:http://hdl.handle.net/11616/12923
Description
Summary:Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.

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