Crystallization of the Skaergaard Intrusion from an Emulsion of Immiscible Iron- and Silica-rich Liquids: Evidence from Melt Inclusions in Plagioclase

• Published in: Journal of Petrology
• Main Authors: Jakobsen, Jakob K., Veksler, Ilya V., Tegner, Christian, Brooks, C. Kent
• Format: Text
• Language: English
• Published: Oxford University Press 2011
• Subjects: Original Papers; Greenland; East Greenland
• Online Access: http://petrology.oxfordjournals.org/cgi/content/short/52/2/345; https://doi.org/10.1093/petrology/egq083

The presence of Fe- and Si-rich liquids found as melt inclusions in apatite and olivine in the Upper Zone of the Skaergaard intrusion, East Greenland, demonstrates the occurrence of liquid immiscibility in the late-stage evolution of tholeiitic magmas in a plutonic setting. However, it remains unclear at which stage of crystallization unmixing began. To constrain the onset and the petrological importance of liquid immiscibility in the Skaergaard and tholeiitic magmas in general, we have studied crystallized melt inclusions entrapped in early primocryst plagioclase. Such melt inclusions become abundant from the top of the Lower Zone and upwards in the Layered Series, in primocryst plagioclase of composition An 54–26 . The daughter phase assemblage is the same in all the inclusions, although the modal proportions of the daughter phases are highly variable: plagioclase (42–59%), clinopyroxene (28–41%), ilmenite (4–9%), magnetite (3–10%), apatite (1–9%) and accessory phases (< 1%). Accordingly, the bulk compositions of reheated and homogenized melt inclusions show large variations in SiO 2 (40–54 wt %), FeO t (7–23 wt %), P 2 O 5 (0–1·9 wt %) and K 2 O (0–2·8 wt %), and have variable CaO/Al 2 O 3 ratios. These variations are best explained by trapping of varying proportions of immiscible iron- and silica-rich melts and demonstrate that liquid immiscibility started in the upper part of the Lower Zone. We conclude that a significant part of the Skaergaard intrusion crystallized from an emulsion of Fe- and Si-rich immiscible melts. The heterogeneous trapping of a mixture of Fe- and Si-rich immiscible liquids in primocryst plagioclase indicates that the dispersed droplets in the Lower and Middle Zones were smaller than the size of the inclusion (< 500 µm). In the Upper Zone, most of the inclusions in apatite are composed of the conjugate end-member liquids, indicating a larger size for the dispersed droplets. Metre-sized pods and layers of melanogranophyre in the upper part of the intrusion are believed to ...