Influence of Dissolved Organic Matter and Fe (II) on the Abiotic Reduction of Pentachloronitrobenzene

Nitroaromatic pesticides (NAPs) are hydrophobic contaminants that can accumulate in sediments by the deposition of suspended solids from surface waters. Fe(II) and dissolved organic matter (DOM), present in suboxic and anoxic zones of freshwater sediments, can transform NAPs in natural systems. We s...

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Bibliographic Details
Main Authors: J Hakala, ERIC WEBER, Y Chin
Format: Text
Language:unknown
Published: 2008
Subjects:
Online Access:http://oaspub.epa.gov/eims/eimsapi.dispdetail?deid=187785
Description
Summary:Nitroaromatic pesticides (NAPs) are hydrophobic contaminants that can accumulate in sediments by the deposition of suspended solids from surface waters. Fe(II) and dissolved organic matter (DOM), present in suboxic and anoxic zones of freshwater sediments, can transform NAPs in natural systems. We studied the reduction of pentachloronitrobenzene (PCNB) to pentachloroaniline (PCA) in controlled studies using Fe(II) and surface water DOM isolates from Pony Lake, Antarctica, and Suwannee River, GA.