Initial Observations of Salt Sieving in Frozen Soil
The role of solutes in the transport of water through frozen porous media is more complicated and subtle than simply lowering the freezing point of the water. This report presents evidence that unfrozen water films in soil act as a semipermeable membrane selectively filtering solutes. The calculated...
Main Author: | |
---|---|
Other Authors: | |
Format: | Text |
Language: | English |
Published: |
1994
|
Subjects: | |
Online Access: | http://www.dtic.mil/docs/citations/ADA286373 http://oai.dtic.mil/oai/oai?&verb=getRecord&metadataPrefix=html&identifier=ADA286373 |
Summary: | The role of solutes in the transport of water through frozen porous media is more complicated and subtle than simply lowering the freezing point of the water. This report presents evidence that unfrozen water films in soil act as a semipermeable membrane selectively filtering solutes. The calculated film thickness at the test temperature (-O.05 deg C) indicates that all solute should pass. The additional influence of anion exclusion arising from a diffuse electrical double layer suggests that solute movement is restricted and a 'salt- sieving' process results. Experimental observations are reported for a specially designed constant-volume ice-sandwich permeameter. Proposed research for a constant-stress ice-sandwich permeameter is presented as a means of overcoming experimental uncertainties of the present system. Frozen soils, Semipermeable membranes, Salt sieving, Soils. |
---|