Pliocene diatom and sponge spicule oxygen isotope ratios from the Bering Sea: isotopic offsets and future directions

Oxygen isotope analyses of different size fractions of Pliocene diatoms (δ 18 O diatom ) from the Bering Sea show no evidence of an isotope offset and support the use of bulk diatom species samples for palaeoceanographic reconstructions. Additional samples containing concentrations of sponge spicule...

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Bibliographic Details
Published in:Climate of the Past
Main Authors: A. M. Snelling, G. E. A. Swann, J. Pike, M. J. Leng
Format: Article in Journal/Newspaper
Language:English
Published: Copernicus Publications 2014
Subjects:
Online Access:https://doi.org/10.5194/cp-10-1837-2014
https://doaj.org/article/896f60bbbea3441aa8645683b169ba2d
Description
Summary:Oxygen isotope analyses of different size fractions of Pliocene diatoms (δ 18 O diatom ) from the Bering Sea show no evidence of an isotope offset and support the use of bulk diatom species samples for palaeoceanographic reconstructions. Additional samples containing concentrations of sponge spicules produce δ 18 O values several per mille (‰) lower than δ 18 O diatom with a calculated mean offset of 3.9‰ ± 1.5. This difference is significantly greater than modern-day variations in water δ 18 O through the regional water column. Despite the potential for oxygen isotope disequilibrium within δ 18 O sponge , there appears to be some similarity between δ 18 O sponge and a global stacked benthic δ 18 O foram record. This highlights the potential for δ 18 O sponge in palaeoenvironmental research at sites where carbonates are not readily preserved.