Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

• Published in: Atmospheric Chemistry and Physics
• Main Authors: Q. Liang, J. M. Rodriguez, A. R. Douglass, J. H. Crawford, J. R. Olson, E. Apel, H. Bian, D. R. Blake, W. Brune, M. Chin, P. R. Colarco, A. da Silva, G. S. Diskin, B. N. Duncan, L. G. Huey, D. J. Knapp, D. D. Montzka, J. E. Nielsen, S. Pawson, D. D. Riemer, A. J. Weinheimer, A. Wisthaler
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2011
• Subjects: Physics; QC1-999; Chemistry; QD1-999; Arctic
• Online Access: https://doi.org/10.5194/acp-11-13181-2011; https://doaj.org/article/53168c3274cb464c9322614635cc7e37

We use aircraft observations obtained during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) mission to examine the distributions and source attributions of O 3 and NO y in the Arctic and sub-Arctic region. Using a number of marker tracers, we distinguish various air masses from the background troposphere and examine their contributions to NO x , O 3 , and O 3 production in the Arctic troposphere. The background Arctic troposphere has a mean O 3 of ~60 ppbv and NO x of ~25 pptv throughout spring and summer with CO decreasing from ~145 ppbv in spring to ~100 ppbv in summer. These observed mixing ratios are not notably different from the values measured during the 1988 ABLE-3A and the 2002 TOPSE field campaigns despite the significant changes in emissions and stratospheric ozone layer in the past two decades that influence Arctic tropospheric composition. Air masses associated with stratosphere-troposphere exchange are present throughout the mid and upper troposphere during spring and summer. These air masses, with mean O 3 concentrations of 140–160 ppbv, are significant direct sources of O 3 in the Arctic troposphere. In addition, air of stratospheric origin displays net O 3 formation in the Arctic due to its sustainable, high NO x (75 pptv in spring and 110 pptv in summer) and NO y (~800 pptv in spring and ~1100 pptv in summer). The air masses influenced by the stratosphere sampled during ARCTAS-B also show conversion of HNO 3 to PAN. This active production of PAN is the result of increased degradation of ethane in the stratosphere-troposphere mixed air mass to form CH 3 CHO, followed by subsequent formation of PAN under high NO x conditions. These findings imply that an adequate representation of stratospheric NO y input, in addition to stratospheric O 3 influx, is essential to accurately simulate tropospheric Arctic O 3 , NO x and PAN in chemistry transport models. Plumes influenced by recent anthropogenic and biomass burning emissions observed during ARCTAS show ...