TCCON and NDACC X CO measurements: difference, discussion and application

• Published in: Atmospheric Measurement Techniques
• Main Authors: M. Zhou, B. Langerock, C. Vigouroux, M. K. Sha, C. Hermans, J.-M. Metzger, H. Chen, M. Ramonet, R. Kivi, P. Heikkinen, D. Smale, D. F. Pollard, N. Jones, V. A. Velazco, O. E. García, M. Schneider, M. Palm, T. Warneke, M. De Mazière
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2019
• Subjects: Environmental engineering; TA170-171; Earthwork. Foundations; TA715-787; Ny-Ålesund; Sodankylä; Ny Ålesund
• Online Access: https://doi.org/10.5194/amt-12-5979-2019; https://doaj.org/article/4758b2954ff3436f9420559b0c56c578

Column-averaged dry-air mole fraction of CO (X CO ) measurements are obtained from two ground-based Fourier transform infrared (FTIR) spectrometer networks: the Total Carbon Column Observing Network (TCCON) and the Network for the Detection of Atmospheric Composition Change (NDACC). In this study, the differences between the TCCON and NDACC X CO measurements are investigated and discussed based on six NDACC–TCCON sites using data over the period 2007–2017. A direct comparison shows that the NDACC X CO measurements are about 5.5 % larger than the TCCON data at Ny-Ålesund, Bremen, and Izaña (Northern Hemisphere), and the absolute bias between the NDACC and TCCON data is within 2 % at Saint-Denis, Wollongong and Lauder (Southern Hemisphere). The hemispheric dependence of the bias is mainly attributed to their smoothing errors. The systematic smoothing error of the TCCON X CO data varies in the range between 0.2 % (Bremen) and 7.9 % (Lauder), and the random smoothing error varies in the range between 2.0 % and 3.6 %. The systematic smoothing error of NDACC data is between 0.1 % and 0.8 %, and the random smoothing error of NDACC data is about 0.3 %. For TCCON data, the smoothing error is significant because it is higher than the reported uncertainty, particularly at Southern Hemisphere sites. To reduce the influence from the a priori profiles and different vertical sensitivities, the scaled NDACC a priori profiles are used as the common a priori profiles for comparing TCCON and NDACC retrievals. As a result, the biases between TCCON and NDACC X CO measurements become more consistent (5.6 %–8.5 %) with a mean value of 6.8 % at these sites. To determine the sources of the remaining bias, regular AirCore measurements at Orléans and Sodankylä are compared to co-located TCCON measurements. It is found that TCCON X CO measurements are 6.1 ± 1.6 % and 8.0 ± 3.2 % smaller than the AirCore measurements at Orléans and Sodankylä, respectively, indicating that the scaling factor of TCCON X CO data should be around 1.0000 instead ...