Grain growth of natural and synthetic ice at 0 °C

Grain growth can modify the microstructure of natural ice, including the grain size and crystallographic preferred orientation (CPO). To better understand grain-growth processes and kinetics, we compared microstructural data from synthetic and natural ice samples of similar starting grain sizes that...

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Bibliographic Details
Published in:The Cryosphere
Main Authors: S. Fan, D. J. Prior, B. Pooley, H. Bowman, L. Davidson, D. Wallis, S. Piazolo, C. Qi, D. L. Goldsby, T. F. Hager
Format: Article in Journal/Newspaper
Language:English
Published: Copernicus Publications 2023
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Online Access:https://doi.org/10.5194/tc-17-3443-2023
https://doaj.org/article/3199e4f28a454cb9bfa0f9d09ffd7c07
Description
Summary:Grain growth can modify the microstructure of natural ice, including the grain size and crystallographic preferred orientation (CPO). To better understand grain-growth processes and kinetics, we compared microstructural data from synthetic and natural ice samples of similar starting grain sizes that were annealed at the solidus temperature (0 ∘ C) for durations of a few hours to 33 d. The synthetic ice has a homogeneous initial microstructure characterized by polygonal grains, little intragranular distortion, few bubbles, and a near-random CPO. The natural ice samples were subsampled from ice cores acquired from the Priestley Glacier, Antarctica. This natural ice has a heterogeneous microstructure characterized by a considerable number of air bubbles, widespread intragranular distortion, and a CPO. During annealing, the average grain size of the natural ice barely changes, whereas the average grain size of the synthetic ice gradually increases. These observations demonstrate that grain growth in natural ice can be much slower than in synthetic ice and therefore that the grain-growth law derived from synthetic ice cannot be directly applied to estimate the grain-size evolution in natural ice with a different microstructure. The microstructure of natural ice is characterized by many bubbles that pin grain boundaries. Previous studies suggest that bubble pinning provides a resisting force that reduces the effective driving force of grain-boundary migration and is therefore linked to the inhibition of grain growth observed in natural ice. As annealing progresses, the number density (number per unit area) of bubbles on grain boundaries in the natural ice decreases, whilst the number density of bubbles in the grain interiors increases. This observation indicates that some grain boundaries sweep through bubbles, which should weaken the pinning effect and thus reduce the resisting force for grain-boundary migration. Some of the Priestley ice grains become abnormally large during annealing. We speculate that the contrast ...