Spin-Hamiltonian Parameters For CrLi3+ Doped In LiNbO3

By using crystal field theory, the spin-Hamiltonian parameters [zero-field splitting D, the giromagnetic factors g (g|| and g⊥) and the first excited state splitting δ(2E)] for the CrLi3+ doped in LiNbO3 have been calculated from the higher-order perturbation formulas. The method used is based on th...

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Bibliographic Details
Published in:Annals of West University of Timisoara - Physics
Main Authors: Avram N.M., Brik M. G., Avram C. N., Ciresan M.G., Andreici E-L.
Format: Article in Journal/Newspaper
Language:English
Published: Sciendo 2012
Subjects:
cr3+
spin-hamiltonian parameters
two-spin-orbit interaction model
Physics
QC1-999
Orca
Online Access:https://doi.org/10.1515/awutp-2015-0001
https://doaj.org/article/293cb5d3a67e48d8ae60e2a0ab0671d3
Description
Summary:By using crystal field theory, the spin-Hamiltonian parameters [zero-field splitting D, the giromagnetic factors g (g|| and g⊥) and the first excited state splitting δ(2E)] for the CrLi3+ doped in LiNbO3 have been calculated from the higher-order perturbation formulas. The method used is based on the two-spin-orbit coupling parameter model, in a cluster approach. The g parameters were also calculated as a second derivative of the energy, method implemented into ORCA computer program. The results were discussed and good agreement with experimental data was demonstrated.

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