Annual variation of strato-mesospheric carbon monoxide measured by ground-based Fourier transform infrared spectrometry

We present long-term time-series of strato-mesospheric CO vertical columns measured from stations located in Antarctica, mid-latitudes and the Arctic, covering the period from 1997–2005. The instrument and the measurement technique allows the separation of tropospheric and strato-mesospheric contrib...

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Bibliographic Details
Main Authors: V. Velazco, S. W. Wood, M. Sinnhuber, I. Kramer, N. B. Jones, Y. Kasai, J. Notholt, T. Warneke, T. Blumenstock, F. Hase, F. J. Murcray, O. Schrems
Format: Article in Journal/Newspaper
Language:English
Published: Copernicus Publications 2007
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Online Access:https://doaj.org/article/1d5a8d6867494987b009271af89a27c1
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Summary:We present long-term time-series of strato-mesospheric CO vertical columns measured from stations located in Antarctica, mid-latitudes and the Arctic, covering the period from 1997–2005. The instrument and the measurement technique allows the separation of tropospheric and strato-mesospheric contributions to the CO column, therefore providing information on the chemistry and dynamics both at low and high altitudes. Data from polar stations show a similar annual variability of strato-mesospheric CO with a strong maximum in late winter and spring. A small enhancement in late summer for some stations, which we call the "summer bulge", can be seen occasionally. Generally, the mid-latitude stations show no significant annual variability of strato-mesospheric CO columns. Measurements were compared with a two-dimensional chemistry-transport model of the middle atmosphere. The annual and latitudinal variations of CO are reproduced well by a model run including thermospheric CO. Comparison with two model scenarios show that the polar winter maximum is due solely to downward transport of thermospheric CO, while CHO x chemistry in the stratosphere could probably contribute to the summer maximum.