Rejuvenating the ocean: mean ocean radiocarbon, CO 2 release, and radiocarbon budget closure across the last deglaciation

Radiocarbon is a tracer that provides unique insights into the ocean's ability to sequester CO 2 from the atmosphere. While spatial patterns of radiocarbon in the ocean interior can indicate the vectors and timescales for carbon transport through the ocean, estimates of the global average ocean...

Full description

Bibliographic Details
Published in:Climate of the Past
Main Authors: L. Skinner, F. Primeau, A. Jeltsch-Thömmes, F. Joos, P. Köhler, E. Bard
Format: Article in Journal/Newspaper
Language:English
Published: Copernicus Publications 2023
Subjects:
Online Access:https://doi.org/10.5194/cp-19-2177-2023
https://doaj.org/article/09c6804ebd8f49f582682f178466e83b
Description
Summary:Radiocarbon is a tracer that provides unique insights into the ocean's ability to sequester CO 2 from the atmosphere. While spatial patterns of radiocarbon in the ocean interior can indicate the vectors and timescales for carbon transport through the ocean, estimates of the global average ocean–atmosphere radiocarbon age offset (B-Atm) place constraints on the closure of the global carbon cycle. Here, we apply a Bayesian interpolation method to compiled B-Atm data to generate global interpolated fields and mean ocean B-Atm estimates for a suite of time slices across the last deglaciation. The compiled data and interpolations confirm a stepwise and spatially heterogeneous “rejuvenation” of the ocean, suggesting that carbon was released to the atmosphere through two swings of a “ventilation seesaw” operating between the North Atlantic and both the Southern Ocean and the North Pacific. Sensitivity tests using the Bern3D model of intermediate complexity demonstrate that a portion of the reconstructed deglacial B-Atm changes may reflect “phase-attenuation” biases that are unrelated to ocean ventilation and that arise from independent atmospheric radiocarbon dynamics instead. A deglacial minimum in B-Atm offsets during the Bølling–Allerød could partly reflect such a bias. However, the sensitivity tests further demonstrate that when correcting for such biases, ocean “ventilation” could still account for at least one-third of deglacial atmospheric CO 2 rise. This contribution to CO 2 rise appears to have continued through the Younger Dryas, though much of the impact was likely achieved by the end of the Bølling–Allerød, indicating a key role for marine carbon cycle adjustment early in the deglacial process. Our global average B-Atm estimates place further new constraints on the long-standing mystery of global radiocarbon budget closure across the last deglaciation and suggest that glacial radiocarbon production levels are likely underestimated on average by existing reconstructions.