Photochemical reactivity of dissolved organic carbon in subarctic lakes along a color gradient ...

Lake–atmosphere carbon exchanges can be significantly affected by photochemical dissolved organic matter (DOM) mineralization. However, our understanding of how increasing allochthonous organic carbon input affects the photoreactivity of DOM per unit of absorbed incoming light is incomplete. Here, w...

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Bibliographic Details
Main Authors: Younes, Hani, Berggren, Martin
Format: Text
Language:unknown
Published: Taylor & Francis 2024
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Online Access:https://dx.doi.org/10.6084/m9.figshare.25848834
https://tandf.figshare.com/articles/journal_contribution/Photo-chemical_reactivity_of_dissolved_organic_carbon_along_a_gradient_of_subarctic_lakes_with_different_color/25848834
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Summary:Lake–atmosphere carbon exchanges can be significantly affected by photochemical dissolved organic matter (DOM) mineralization. However, our understanding of how increasing allochthonous organic carbon input affects the photoreactivity of DOM per unit of absorbed incoming light is incomplete. Here, we measured the absorption of ultraviolet (UV) light and subsequent photochemical DOM decay in 148 lakes within the subarctic region of Abisko, Sweden. These lakes range from brown-water lakes with allochthonous input from mires to tundra clear-water lakes with relatively more autochthonous input. We used fluorescence excitation–emission matrix analysis to assess the DOM chemical composition to determine how increasing colored DOM (CDOM) affects photomineralization. We found that the photo decay rates in absolute values were positively correlated to CDOM. However, the photo decay per unit of absorbed light energy did not increase with increasing CDOM; rather, it showed a weak decreasing trend. Fluorescence analyses ...