Five-dimensional imaging of freezing emulsions with solute effects

The interaction of objects with a moving solidification front is a common feature of many industrial and natural processes such as metal processing, the growth of single-crystals, the cryopreservation of cells, or the formation of sea ice. Solidification fronts interact with objects with different o...

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Bibliographic Details
Main Authors: Dedovets, Dmytro, Monteux, Cécile, Deville, Sylvain
Format: Text
Language:unknown
Published: arXiv 2017
Subjects:
Online Access:https://dx.doi.org/10.48550/arxiv.1710.01032
https://arxiv.org/abs/1710.01032
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Summary:The interaction of objects with a moving solidification front is a common feature of many industrial and natural processes such as metal processing, the growth of single-crystals, the cryopreservation of cells, or the formation of sea ice. Solidification fronts interact with objects with different outcomes, from the total rejection to their complete engulfment. We image the freezing of emulsions in 5D (space, time, and solute concentration) with confocal microscopy. We show the solute induces long-range interactions that determine the solidification microstructure. The local increase of solute concentration enhances premelting, which controls the engulfment of droplets by the front and the evolution of grain boundaries. Freezing emulsions may be a good analogue of many solidification systems where objects interact with a solidification interface. : 23 pages, 4 figures, 31 references